一种用于3D打印的阻燃型生物基TPU及其制备方法

By preparing a TPU material containing ozonated palm oil-based polyols and vegetable oils, and adding dianhydride chain extenders and phenoxycyclophosphamide, the flammability problem of polyurethane materials in 3D printing was solved, achieving improved high flame retardancy and mechanical properties, making it suitable for various application scenarios.

CN116769125BActive Publication Date: 2026-07-17SHANDONG LEAD CHEM CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG LEAD CHEM CO LTD
Filing Date
2023-07-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyurethane materials are flammable in 3D printing. Adding flame retardants reduces their mechanical properties and thermal stability, making them unsuitable for 3D printing requirements.

Method used

TPU was prepared by compounding ozonated palm oil-based polyol with vegetable oil and reacting it with diisocyanate. Diacid anhydride chain extenders and phenoxycyclophosphamide were added to form a network structure and hydrogen bond crosslinking, thereby improving the mechanical properties and flame retardant properties of the material.

Benefits of technology

The prepared flame-retardant bio-based TPU material exhibits excellent mechanical properties, thermal stability, and flame-retardant properties during 3D printing, preventing material fracture and improving melt strength and flowability. It is suitable for applications such as medical devices, coatings, parts, and tires.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure BDA0004321939310000081
    Figure BDA0004321939310000081
Patent Text Reader

Abstract

本发明涉及3D打印材料技术领域,具体公开一种用于3D打印的阻燃型生物基TPU及其制备方法。包括如下重量份数的各组分:臭氧化棕榈油基多元醇45~65份、植物油10~20份、二异氰酸酯25~40份、苯氧基环磷腈2~5份、二酸酐类扩链剂5~10份和催化剂0.4~1.0份;其中,所述臭氧化棕榈油基多元醇经氧化反应过程并通过硼氢化钠在甲醇‑乙酸乙酯体系中还原臭氧化棕榈油制备得到。本发明以含有高反应活性伯羟基的臭氧化棕榈油基多元醇为原料,并将其和植物油复配,与二异氰酸酯反应制备得到具有优异的力学性能、热稳定性和阻燃性能的棕榈油基聚氨酯弹性体,有效避免在打印时出现物料断裂或难以挤出的情况。
Need to check novelty before this filing date? Find Prior Art