一种孔径均匀的低密度高PPI三维网络结构聚氨酯海绵及其制备方法

By controlling the use of isocyanate-terminated prepolymers and surfactants, the growth of foam cells is regulated, and a three-dimensional network structure polyurethane sponge with uniform pore size, low density, and high PPI value is prepared. This solves the problems of uneven pore size and excessive density in the existing technology and is suitable for electrode materials for new energy batteries.

CN116769127BActive Publication Date: 2026-07-17HUBEI SHIFENG NEW MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUBEI SHIFENG NEW MATERIALS CO LTD
Filing Date
2023-07-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to produce polyurethane foams with uniform pore size, low density, and high PPI value in a three-dimensional network structure, resulting in slow charging and discharging speeds, excessively high density, and uneven pore size.

Method used

By controlling the viscosity and NCO value of the isocyanate-terminated prepolymer, using supersaturated gas to form homogeneous nucleation sites, and combining the selection of surfactants and foaming agents, the pore size after cell growth termination can be controlled to prepare a three-dimensional network structure polyurethane foam with low density and high PPI value.

Benefits of technology

A high PPI polyurethane sponge with uniform pore size and low density was prepared, exhibiting good pore size uniformity and strength. It is suitable for electrode materials in new energy batteries, improving charging and discharging speed and corrosion resistance.

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Abstract

本发明公开了一种孔径均匀的低密度高PPI三维网络结构聚氨酯海绵及其制备方法;三维网络结构聚氨酯海绵PPI值为130~250,密度为35~80kg / m3,拉伸强度为300~800KPa,伸长率为250%~400%。相比普通低PPI值三维网络结构聚氨酯海绵,以该种孔径均匀的低密度高PPI值三维网络结构聚氨酯海绵为基材,先经过PVD导电化处理形成导电海绵,然后经过电沉积金属 / 金属合金,最后经过高温氧化烧蚀、氢气保护还原等工艺,制备的泡沫金属 / 多孔合金电极材料,具有比表面积大、催化活性中心多、强度韧性及耐腐蚀性能好等特性,所制备多孔金属电极材料充放电速度快,极大地满足了动力电池和储能电站对高充放电速度电极材料的要求。
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