一种补锂剂及其制备方法与应用

By embedding lithium carbonate in superabsorbent resin and combining it with porous carbon materials, the problems of lithium-ion consumption and low electrochemical activity of self-sacrificing materials in lithium-ion batteries are solved, the energy density and cycle performance of batteries are improved, and low-cost lithium replenishment agent preparation is achieved.

CN116799184BActive Publication Date: 2026-07-17HEFEI GUOXUAN HIGH TECH POWER ENERGY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HEFEI GUOXUAN HIGH TECH POWER ENERGY
Filing Date
2023-07-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing lithium-ion batteries, the solid electrolyte film formed on the negative electrode surface during the formation stage consumes lithium ions, leading to capacity decay of the positive electrode material and a decrease in battery energy density. The self-sacrificing material has low electrochemical activity, and the lattice oxygen generated during decomposition erodes the electrolyte, resulting in poor contact at the reaction contact points and affecting battery performance.

Method used

By encapsulating lithium carbonate in superabsorbent resin and combining it with porous carbon materials, the conductivity and electrochemical activity of lithium carbonate are improved. Furthermore, the porous carbon is used to adsorb lattice oxygen and inhibit its reaction with the electrolyte, thus preparing a lithium replenishing agent.

Benefits of technology

It significantly improves the conductivity and electrochemical activity of lithium carbonate, enhances the energy density and cycle performance of batteries, reduces the decomposition voltage, and is suitable for mass production without the need to upgrade existing lithium battery production lines.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供了一种补锂剂及其制备方法与应用。本发明补锂剂的制备方法,包括如下步骤:1)将高吸水树脂加入到碳酸锂溶液中,混合,得到凝胶复合物;2)将所述凝胶复合物进行干燥处理,得到前驱体粉末;3)将所述前驱体粉末在惰性条件下烧结,即得到补锂剂。本发明通过高吸水树脂的包埋作用实现碳酸锂和多孔碳材料的均匀复合,大幅提升碳酸锂的导电性和电化学活性;并且利用多孔碳对晶格氧的吸附作用,抑制晶格氧和电解液的反应,从而提升碳酸锂分解过程中的稳定性,以应用于制备锂离子电池中。
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