一种从锂矿中回收锂的方法及其应用

By combining lithium ore with sodium sulfate, ferric sulfate, and calcium oxide through mixed roasting and extracting with HBL121 and 12-crown ether-4 extractants, the problems of high energy consumption and low extraction rate of existing lithium ore extraction methods have been solved, achieving efficient and low-cost lithium resource recovery and producing high-purity lithium carbonate.

CN116814986BActive Publication Date: 2026-07-17FANGYUAN ENVIRONMENG CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
FANGYUAN ENVIRONMENG CO LTD
Filing Date
2023-07-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium extraction methods from lithium ore suffer from problems such as high energy consumption, low lithium extraction rate, stringent process requirements, and high equipment corrosivity. Furthermore, the extractants commonly used in extraction methods are prone to corroding equipment under acidic conditions, resulting in significant lithium loss.

Method used

Lithium ore was roasted with sodium sulfate, ferric sulfate, and calcium oxide to produce lithium sulfate and lithium oxides. These were then extracted with HBL121 and 12-crown ether-4 extractants. High-purity lithium carbonate was prepared by multi-stage countercurrent extraction and back-extraction.

Benefits of technology

By increasing the lithium leaching rate to over 94% under low-temperature roasting conditions, energy consumption is reduced, equipment corrosion is decreased, lithium extraction rate and purity are improved, the purity requirements for battery-grade lithium carbonate are met, and the efficient recycling and utilization of lithium resources are promoted.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供一种从锂矿中回收锂的方法及其应用。所述方法包括以下步骤:将锂矿石、硫酸钠、硫酸铁、氧化钙混合,得混合料;将所述混合料进行焙烧,得焙烧料;将所述焙烧料进行浸出,对所得浸出液除杂,得含锂溶液;对所述含锂溶液进行萃取和反萃,得富锂溶液。本发明方法提锂收率高,浸出液中杂质元素含量低,能够降低提锂成本,促进从锂矿中提锂的工业化应用。本发明还提供所述方法在制备电池级碳酸锂或锂离子电池中的应用。
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