一种掺杂型高镍三元正极材料及其制备方法

By introducing tungsten and niobium doping into lithium-ion battery cathode materials and combining it with a segmented calcination process, a high-nickel ternary cathode material with excellent chemical properties and a uniform spherical structure was prepared. This solved the problem of decreased cycle stability and safety performance of the material under high nickel content, and achieved high capacity retention and rapid kinetic performance.

CN116845223BActive Publication Date: 2026-07-17HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD
Filing Date
2023-08-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium-ion battery cathode materials, such as nickel-cobalt-manganese ternary materials and nickel-cobalt-aluminum ternary materials, exhibit decreased cycle stability and safety performance after increasing the Ni content, and their sphericity and particle size are not uniform during the preparation process.

Method used

By introducing tungsten and doping with niobium, a surface coating layer of LiNbO3/Li3NbO4 is formed through heat treatment at a specific temperature. Combined with a segmented calcination process, a uniform spherical high-nickel ternary cathode material is prepared, which improves the structural stability and lithium-ion diffusion performance of the material.

Benefits of technology

It improves the cycling stability and rate performance of the material, reduces capacity loss in the first cycle, and enhances capacity retention during long cycles.

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Abstract

本发明公开了一种掺杂型高镍三元正极材料及其制备方法,该材料的制备包括以下步骤:将镍源、钴源、钨源、表面活性剂、水、氨基羧酸盐、水解助剂混合均匀,得到混合液;将混合液在密闭条件下于150‑200℃温度中进行陈化,分离获得沉降物;沉降物经洗涤后依次进行打浆、砂磨,最后经喷雾干燥获得前驱体;将前驱体与氧化铌、锂源充分混合研磨,获得混合粉末,经煅烧得到最终产物。本发明制备的正极材料中铌一部分保留在一次颗粒表面形成LiNbO3 / Li3NbO4表面包覆层,减少首圈容量损失并提高倍率性能;一部分扩散到体相,从而提高了长循环过程中的容量保持率。本发明制备的材料呈均匀球形,具有优异的首次放电容量和循环稳定性。
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