一种超亲水光催化自清洁陶瓷复合膜及其制备方法与应用

By preparing TiO2 nanotubes on the surface of ceramic membranes for modification, the problems of membrane fouling and low photocatalytic efficiency in the treatment of high-concentration emulsified oil wastewater were solved, achieving efficient oil-water separation and catalyst recovery.

CN116850796BActive Publication Date: 2026-07-17TIANJIN POLYTECHNIC UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TIANJIN POLYTECHNIC UNIV
Filing Date
2023-06-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for efficiently treating high-concentration, high-viscosity emulsified oil wastewater, and traditional membrane separation and photocatalysts suffer from problems such as membrane fouling, high cost, and difficulty in recycling.

Method used

Hollow fiber or flat ceramic membranes were prepared using a solvent-free phase inversion method as the base membrane. TiO2 nanotubes were prepared by hydrothermal method and deposited on the surface of the base membrane by in-situ precipitation. Combined with gradient sintering method, TiO2 nanotube modified ceramic composite membranes were prepared, which improved the hydrophilicity and photocatalytic self-cleaning performance of the membrane.

Benefits of technology

It improves membrane separation efficiency, reduces membrane fouling, broadens the application scope of photocatalysis technology, and provides reliable support for catalysts, facilitating recycling.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及一种用于含油废水的分离膜及其制备方法,特别涉及一种用于实际油田采出水的陶瓷复合膜及其制备方法与应用,即首先以非溶剂相转化法(NIPS)法制备的中空纤维陶瓷膜或平板膜为基膜,在碱性环境下通过水热法合成出具有高长径比的中空TiO2纳米管光催化剂,随后采用原位沉淀方法将其沉积在基膜表面,再通过梯度烧结法,制备出TiO2纳米管改性的陶瓷复合膜。TiO2纳米管改性的陶瓷复合膜抗污染效果更好,分离效率更高且具有优异的模拟太阳光催化自清洁性能,从而提高膜的重复使用性;此外,固载到膜表面的光催化剂,比表面积大,有利于催化降解膜表面的污染物、便于回收利用且不产生二次污染,拓宽了光催化技术的应用范围。
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