一种具有三维结构的共价有机框架材料及其合成方法

By designing the Miyaura borylation reaction of bromine-containing tetrahedral organic ligands and pinacol borate linear symmetric units, a low-cost and highly stable three-dimensional covalent organic framework material was successfully synthesized, solving the problems of complex preparation and insufficient stability in existing technologies and expanding its application potential in multiple fields.

CN116854894BActive Publication Date: 2026-07-17HENAN UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HENAN UNIV OF SCI & TECH
Filing Date
2023-08-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to effectively construct three-dimensional covalent organic framework materials due to their complex and costly preparation processes and insufficient stability.

Method used

A covalent organic framework material with a three-dimensional structure was synthesized by using a bromine-containing tetrahedral organic ligand and a linear symmetric building block containing borate pinacol ester via the Miyaura borylation reaction. The reaction was carried out using a specific ratio of raw materials and catalyst under suitable temperature and time conditions.

Benefits of technology

A three-dimensional porous network structure material with low cost and simple preparation process has been realized. It has high thermal and chemical stability and is suitable for fluorescence detection, photocatalysis, electrocatalysis and environmental applications.

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Abstract

本发明提供一种具有三维结构的共价有机框架材料及其合成方法,属于有机多孔材料的合成领域。所述合成方法,包括两步:第一步是以四苯基甲烷和液溴为原料,得到淡黄色粉末固体四(4‑溴苯)甲烷;第二步是以四(4‑溴苯)甲烷和4,7‑双(4,4,5,5‑四甲基‑1,3,2‑二氧杂戊硼烷‑2‑基)‑2,1,3‑苯并噻二唑为原料,以DMF为溶剂,N2保护,催化剂条件下,采用油浴加热的方法合成了深黄色粉末COF‑TBPM‑BBT,一种具有三维结构的共价有机框架材料。本反应具有合成工艺简单,反应条件温和,产率高,产物热稳定性和化学稳定性强等优点,在荧光检测、光催化、电催化、环境化学、药学医疗等领域有广泛的应用前景。
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