双核基三节点MOF材料及其制法与在制备暖白光LED中的应用

By preparing a binuclear-based three-node MOF material [Zn2(OH)(dttd)1.5(tpt)]n as a single-component light-converting agent, the problems of spectral imbalance and blue light hazard in existing white LEDs were solved, achieving high-efficiency light emission and energy-saving and environmentally friendly effects of warm white LEDs at low power.

CN116948196BActive Publication Date: 2026-07-17CHONGQING NORMAL UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHONGQING NORMAL UNIVERSITY
Filing Date
2023-06-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The rare earth-based phosphors used in existing white LEDs have problems such as limited resources, difficulty in quantitative modulation, uneven spectrum and significant blue light hazard, making it difficult to prepare high-efficiency warm white LEDs.

Method used

A three-dimensional coordination polymerization MOF material, [Zn2(OH)(dttd)1.5(tpt)]n, was prepared by solvothermal synthesis using a binuclear-based three-node MOF material as a single-component light-converting agent. This material is then used in warm white LEDs driven by low power.

Benefits of technology

It achieves the emission of warm white light at low power, has efficient downconversion performance, covers the red, green and cyan wavelengths, reduces blue light hazards, and has excellent energy-saving and environmental protection properties.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN116948196B_ABST
    Figure CN116948196B_ABST
Patent Text Reader

Abstract

本发明提供了一种双核基三节点MOF材料,其化学通式为[Zn2(OH)(dttd)1.5(tpt)]n,属于三斜晶系,空间群为Pī,晶胞参数所述化学通式中,两种有机组份都有杂环,dttd2‑是刚性的稠噻吩基羧酸H2dttd脱去2个质子所得,所述H2dttd结构如式Ⅰ所示;tpt结构如式Ⅱ所示,该材料结构里存在氢氧根桥联的双核簇[Zn(OH)N3O3],有机组份桥联双核簇形成3,4,4‑连接的三节点配位聚合型MOF,拓扑符号为{6.82}{85.10}{62.84};热稳定较高,产率可达约68.9%;该MOF材料作为单成份转光剂,所制暖白光LED具有能耗低、近连续光谱、低蓝光危害等优良性能。
Need to check novelty before this filing date? Find Prior Art