一种环氧悬挂链结构改性硅橡胶及其复合材料

By introducing vinyl-functionalized epoxy resin and inorganic materials into PDMS, a modified silicone rubber with a suspended chain structure was prepared, which solved the problem of insufficient mechanical properties and ablation resistance of PDMS in flexible thermal protection materials and achieved a significant improvement in the material's performance.

CN117004228BActive Publication Date: 2026-07-17SICHUAN UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SICHUAN UNIV
Filing Date
2023-06-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polydimethylsiloxane (PDMS) materials have insufficient mechanical and adhesive properties in flexible thermal protection materials, and their ablation resistance does not meet the requirements.

Method used

By introducing vinyl-functionalized epoxy resin (EAP) to modify PDMS, EAP@PDMS material is formed, and then combined with inorganic materials such as silica and carbon fiber to prepare a modified silicone rubber composite material with a suspended chain structure.

Benefits of technology

It significantly improves the mechanical properties, adhesion properties and ablation resistance of the material, with tensile strength increased by 575%, elongation at break increased by 155%, adhesive strength increased by 183%, linear ablation rate reduced by 80.1%, and ablation resistance significantly improved.

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Abstract

本发明提供了一种基于环氧悬挂链结构的改性硅橡胶及其复合材料,属于先进材料领域。本发明通过具有大空间位阻的悬挂链环氧对硅橡胶分子结构进行改性,制备了一种基于环氧悬挂链结构的改性硅橡胶:EAP@PDMS。与纯PDMS相比,EAP@PDMS材料不仅机械性能和粘接性能得到了显著提升,耐烧蚀性能也显著增强。此外,本发明还发现引入SiO2和CF能够进一步改善EAP@PDMS材料的耐烧蚀性能。本发明提供的改性硅橡胶材料不仅具有优异的柔性变形能力,同时具有优异的机械性能和耐烧蚀性能,在航空航天等领域作为热防护涂层和柔性烧蚀防热材料具有很好的应用前景。
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