一种高导电性透明导电电极及其制备方法和应用

By etching patterned grooves and embedding metal grid lines on the transparent substrate surface of perovskite solar cells, combined with a metal bonding layer and an oxide layer, the series resistance problem of transparent conductive electrodes in large-size perovskite cells is solved, achieving a balance between high conductivity and transparency, thus improving cell efficiency and applicability.

CN117042479BActive Publication Date: 2026-07-17PEKING UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PEKING UNIV
Filing Date
2023-08-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

When existing perovskite solar cells are scaled up to large sizes, the series resistance of the transparent conductive electrode becomes too high, leading to a decrease in cell efficiency. Existing solutions cannot balance light transmittance and conductivity, and there are conflicts in the fabrication process and manufacturing sequence.

Method used

A highly conductive transparent conductive electrode is formed by etching patterned grooves on the surface of a transparent substrate and embedding metal grid lines, combined with a metal bonding layer and a metal oxide layer. The conductivity is improved by combining the metal grid lines with the metal bonding layer, and the degree of incident light scattering is adjusted by designing the geometric pattern of the metal grid lines and the thickness of the bonding layer.

Benefits of technology

It significantly improves the conductivity of the transparent electrode, reduces photocurrent loss, expands the application range of perovskite solar cells, improves the performance of cells from small to large sizes, and is compatible with low-temperature processes, making it suitable for perovskite solar cells of various sizes.

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Abstract

本发明提供了一种高导电性透明导电电极及其制备方法和应用,属于光电功能器件技术领域。本发明提供的高导电性透明导电电极包括透明衬底,所述透明衬底表面具有图案化凹槽;嵌于所述图案化凹槽中的金属栅线,所述金属栅线的高度大于所述图案化凹槽的深度;覆盖所述金属栅线和透明衬底表面的金属联结层;位于所述金属联结层表面的金属氧化物层,所述金属氧化物为所述金属联结层的氧化物。本发明利用金属栅线与金属联结层、金属氧化物层结合的方式极大地提高透明电极的导电性。同时,金属栅线微凸起的结构可以增大入射光在钙钛矿太阳能电池内部的散射以及吸光层的表面积,减小因为栅线遮光导致的光电流损失。
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