一种金纳米线的无模板电化学合成方法

By using a template-free electrochemical synthesis method with reduction voltage and alkynyl ligands, uniform growth of ultrafine gold nanowires was achieved, solving the problem of difficult preparation in traditional methods, simplifying the experimental process and increasing the length of the nanowires.

CN117051436BActive Publication Date: 2026-07-17NANJING TECH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANJING TECH UNIV
Filing Date
2022-05-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing electrochemical deposition methods face difficulties in preparing uniformly morphological ultrafine nanostructures under template-free conditions, and traditional wet chemical methods struggle to precisely control the reduction rate and morphology.

Method used

A template-free electrochemical synthesis method was adopted, which uses reduction voltage instead of reducing agent and combines alkynyl ligands to passivate the gold surface. By precisely controlling the reduction rate and applying reduction potential for a long time, gold nanowires were spontaneously induced to grow.

Benefits of technology

Uniform growth of ultrafine gold nanowires was achieved, with lengths far exceeding those of traditional wet chemical methods, simplifying the experimental process and making them suitable for industrial applications.

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Abstract

本发明涉及一种金纳米线的无模板电化学合成方法,属于纳米材料合成领域。该方法利用三电极体系,将前驱体氯金酸和炔基配体的混合溶液作为电解液,施加电压控制生长了炔基配体修饰的金纳米线。该方法通过给反应体系施加还原电压,替代了传统湿化学合成方法中还原剂的作用。通过精细调控还原电位以及长时间施加还原电压,可以制备出长度是传统湿化学合成方法无法企及的纳米线。该方法操作简单灵活,施加的还原区间范围广,基底上得到的金纳米纯度高,形貌均一且分布均匀。
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