联吡啶双膦铜配合物、其制备方法及其应用

The preparation of bipyridine bisphosphine copper complexes via coordination reactions solves the problems of complex synthesis methods and high costs, and realizes the preparation of efficient and environmentally friendly bipyridine bisphosphine copper complexes with good fluorescence properties and thermal stability, promoting their application in photocatalysts and optical materials.

CN117069764BActive Publication Date: 2026-07-17SICHUAN UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SICHUAN UNIV
Filing Date
2023-08-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to effectively develop novel bipyridine bisphosphine complexes with high thermal stability and fluorescence properties, and the synthesis methods are complex and costly, which limits their widespread application in practice.

Method used

A simple and inexpensive preparation method is used to coordinate copper halide with 3,3'-bis[(diphenylphosphino)methyl]-2,2'-bipyridine ligand in a mixed solvent to form a bipyridine bisphosphine copper complex with a four-coordinate twisted tetrahedral configuration.

Benefits of technology

The prepared bipyridine bisphosphine copper complex exhibits good fluorescence properties and thermal stability, making it suitable for photocatalysts and optical materials. Furthermore, the production process is environmentally friendly and efficient, meeting the requirements of sustainable development.

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Abstract

本发明涉及金属配合物技术领域,具体而言,涉及联吡啶双膦铜配合物、其制备方法及其应用。联吡啶双膦铜配合物选自下述结构式所示的化合物:其中X表示卤素。本发明实施例提供的新型联吡啶双膦铜配合物同时具有较好的荧光性能和热稳定性,可用于光催化剂和光学材料。该制备方法反应条件温和,制备过程简单,成本低廉。
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