一种高电荷量纤维素纳米晶、其制备方法、包括其的油砂清洗剂及使用方法

The oil sand cleaning agent, which combines high-charge cellulose nanocrystals with nonionic surfactants, solves the problems of high energy consumption and low oil removal efficiency in oil sand cleaning. It achieves efficient cleaning of oily mud and sand at room temperature, is suitable for both freshwater and seawater environments, and has good oil removal effect and resource recycling capability.

CN117069871BActive Publication Date: 2026-07-17天津永续新材料有限公司 +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
天津永续新材料有限公司
Filing Date
2023-08-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for cleaning oil sands suffer from high energy consumption, low oil removal efficiency, difficult post-processing, and potential environmental hazards, especially in oil spills near coastlines. Traditional cleaning agents require auxiliary heating and are ineffective in both freshwater and seawater environments.

Method used

A high-charge cellulose nanocrystal compounded with a nonionic surfactant is used to form an oil sand cleaning agent. When used at room temperature, the high-charge cellulose nanocrystal repulsion between itself and the negatively charged sand particles improves the oil removal efficiency and maintains stability in oily emulsions, simplifying the post-treatment process.

Benefits of technology

It achieves efficient cleaning of oily mud and sand at room temperature, reduces the amount of cleaning agent used, shortens the post-treatment time, and is suitable for both freshwater and seawater environments. It has a good oil removal effect, especially in oil spill accidents near the coastline, and has a strong resource recycling capacity.

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Abstract

本发明提供了一种高电荷量纤维素纳米晶、其制备方法、包括其的油砂清洗剂及使用方法,制备方法包括:纸浆和高碘酸盐溶液混合,在避光条件下搅拌进行氧化反应,得到氧化产物;向氧化产物中加入多元醇继续反应得到反应液,多次过滤洗涤得到氧化纸浆;氧化纸浆、亚氯酸盐、氧化剂和去离子水混合,在搅拌条件下发生氧化反应得到悬浮液,进行一次离心分离,向上清液加入乙醇直至无沉淀物生成,经二次离心分离得到沉淀物;将沉淀物分散于去离子水中形成分散液,透析纯化得到高电荷量纤维素纳米晶。本发明通过携带负电荷的高电荷量纤维素纳米晶与少量的非离子表面活性剂进行复配,得到了一种高效、环保、低能耗且易于后处理的油砂清洗剂。
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