一种钌稀土固溶体氧化物电催化剂及其制备方法

Ruthenium rare earth solid solution oxide Ru1-xMxO2 catalyst was prepared by low-temperature molten salt method, which solved the problems of stability and high cost of Ru-based catalysts and achieved efficient and stable hydrogen production performance through water electrolysis and mass production.

CN117107277BActive Publication Date: 2026-07-17PEKING UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PEKING UNIV
Filing Date
2023-09-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing Ru-based catalysts suffer from insufficient stability, high cost, and difficulty in mass production during water electrolysis for hydrogen production. Furthermore, their insufficient mass transfer and conductivity hinder their promotion in industrial applications.

Method used

Ruthenium rare earth solid solution oxide Ru1-xMxO2 catalyst was prepared by a low-temperature molten salt-assisted synthesis method. Ruthenium trichloride and rare earth metal nitrates were rapidly reacted in molten salt to form a layered porous structure with a particle size of 3-4 nm, which is suitable for the oxygen evolution reaction of water electrolysis.

Benefits of technology

A ruthenium-based catalyst with high activity and high stability has been developed, which can achieve high current density at low cell voltage and maintain long-term stability at high current density, thereby reducing production costs and enabling mass production.

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Abstract

本发明公开了一种钌稀土固溶体氧化物电催化剂及其制备方法。所述电催化剂用于电催化分解水制氢的阳极反应,是由钌稀土固溶体氧化物Ru1‑xMxO2细晶粒组成的片层状富孔结构,其中M选自镧系稀土元素中的一种,0.04≤x≤0.27。该电催化剂以三氯化钌和稀土硝酸盐作为Ru和M的前驱体,基于低温熔融盐辅助合成方法制备,尺寸均一、成分可控、电催化活性高、稳定性高,制备方法简单快速,适用于各类钌稀土元素催化剂的普适性合成,且可实现批量化制备,为推进电解水催化剂的产业化提供重要的技术保障。
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