一种基于铜基多金属微电极的电化学传感器及其制备方法与应用方法

By depositing gold nanoparticles in situ on the surface of a copper microelectrode to form a Cu-Au bimetallic electrode, the problems of complex and costly preparation of noble metal electrodes are solved, the catalytic performance and stability of the electrochemical sensor are improved, and efficient glucose detection is achieved.

CN117110392BActive Publication Date: 2026-07-17CENT SOUTH UNIV +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2023-07-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the preparation process of noble metal electrodes is complex and costly. The catalytic ability of a single noble metal electrode is insufficient. The active sites are severely lost during the modification of nanomaterials. The bonding of multi-metal electrodes is not strong, the conductivity is weak and they are easy to fall off. The preparation process is cumbersome.

Method used

A copper-based multimetal microelectrode was used to deposit gold nanoparticles in situ on the surface of the copper microelectrode via an electrochemical method. By adjusting the crystal plane ratio of the gold nanoparticles, a Cu-Au bimetallic electrode was formed, which simplified the preparation process and improved the catalytic activity and stability.

Benefits of technology

It achieves efficient glucose detection with a wide linear detection range, low detection limit, significantly increased electrode active area, good stability, and reduced cost of using precious metals.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN117110392B_ABST
    Figure CN117110392B_ABST
Patent Text Reader

Abstract

本发明提供一种基于铜基多金属微电极的电化学传感器及其制备方法与应用方法。电化学传感器为三电极体系传感器,对电极是铂丝电极,参比电极是饱和甘汞电极,铜基多金属微电极电化学传感器的工作电极为铜微电极;铜微电极表面有电化学法一步制备的金纳米颗粒。工作电极的制备包括以下步骤:选用或制备铜微电极;采用三电极系统,以铂丝为对电极,饱和甘汞电极为参比电极,铜微电极为工作电极,通过电化学法在铜微电极表面沉积金纳米颗粒。本发明构建了一种以柱形铜微电极为基体,纳米金为修饰物的电化学检测传感用的双金属电极。通过局部电化学法直接制备表面有微纳结构的微米尺度电极,具有大活性面积可增大电极与葡萄糖反应的活性位点。
Need to check novelty before this filing date? Find Prior Art