锂硫电池正极材料的制备方法、正极材料、正极片及锂硫电池

By introducing functional groups to modify the surface of carbon nanotubes and loading them with platinum, the electron distribution of the nanotubes was adjusted, thus solving the problem of catalyst deactivation during cycling of lithium-sulfur battery cathode materials. This resulted in a cathode material with high activity and high stability, improving the overall performance of lithium-sulfur batteries.

CN117133894BActive Publication Date: 2026-07-17TSINGHUA SHENZHEN INTERNATIONAL GRADUATE SCHOOL

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TSINGHUA SHENZHEN INTERNATIONAL GRADUATE SCHOOL
Filing Date
2023-08-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium-sulfur battery cathode materials suffer from catalyst deactivation during cycling due to strong interactions between the catalyst and polysulfides, making it difficult to meet the requirements for high-performance and stable applications.

Method used

By introducing functional groups to modify the surface of carbon nanotubes and loading them with platinum, functionalized carbon nanotubes are formed. The d-electron distribution of platinum is adjusted to suppress its excessive reaction with lithium polysulfides, thus preparing a cathode material with high activity and high stability.

Benefits of technology

It improves the cycle stability of lithium-sulfur batteries and the catalytic conversion capability of lithium polysulfides, thereby enhancing the utilization rate of cathode materials and the overall performance of the battery.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN117133894B_ABST
    Figure CN117133894B_ABST
Patent Text Reader

Abstract

本申请提供了一种锂硫电池正极材料的制备方法、正极材料、正极片及锂硫电池,包括:将碳纳米管和第一还原剂加入第一有机溶剂中,反应后得到羟基化碳纳米管;将羟基化碳纳米管和含卤化合物加入第二有机溶剂中得到卤基化碳纳米管;将卤基化碳纳米管和含官能团化合物加入水中,得到官能团改性的碳纳米管;将官能团改性的碳纳米管加入铂金属盐溶液和第二还原剂中,并加入碱液,以调节pH为11~14,进行水热反应,得到复合材料,复合材料为负载有金属铂的功能化碳纳米管;在惰性气体下,将复合材料与硫粉混合,加热,得到正极材料。本申请中在碳纳米管上接枝的官能团与金属铂相互作用,保持金属铂的催化活性并提高金属铂的耐硫化性能。
Need to check novelty before this filing date? Find Prior Art