一种负极活性材料、二次电池及电子装置

By using silicon-based composite materials in lithium-ion batteries, controlling the Raman spectrum ratio and powder conductivity, and forming a complete conductive network, the problem of increased porosity in the negative electrode caused by silicon material expansion is solved, thus improving the battery's cycle performance and expansion performance.

CN117174888BActive Publication Date: 2026-07-17NINGDE AMPEREX TECHNOLOGY LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NINGDE AMPEREX TECHNOLOGY LTD
Filing Date
2023-09-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The volume expansion of silicon materials during the charging and discharging process in lithium-ion batteries leads to an increase in the porosity of the negative electrode sheet, affecting the battery's expansion performance and cycle life.

Method used

A silicon-based composite material, including a silicon matrix, a conductive agent, and a polymer, is used. By adjusting the Raman spectral ratio A and the powder conductivity, a complete conductive network is formed, releasing the stress caused by silicon expansion and alleviating the expansion of the negative electrode sheet.

Benefits of technology

It improves the cycle performance and expansion performance of secondary batteries, reduces the increase in porosity of negative electrode sheets caused by silicon expansion stress, and improves battery stability and lifespan.

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Abstract

本申请提供了一种负极活性材料、二次电池及电子装置。负极活性材料包括硅基复合材料,硅基复合材料包括硅基体、导电剂和聚合物,导电剂和聚合物位于硅基体的至少部分表面,硅基复合材料的粉末电导率为0.03S / cm至0.1S / cm。将具有上述特征的负极活性材料应用于二次电池,通过调控A的值和硅基复合材料的粉末电导率在本申请范围内,能够使得负极活性材料具有完整的导电网络的同时,释放因硅膨胀产生的应力,减少因硅膨胀释放应力导致的负极极片孔隙率的增加量,从而缓解硅负极极片的膨胀,改善二次电池的循环性能和膨胀性能。
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