A distillation packing for treating tritium-containing wastewater and its preparation method

By modifying the metal wire mesh packing and loading it with MOFs, the low efficiency problem caused by the hydrophobicity of conventional packing was solved, achieving efficient and safe separation of tritium-containing wastewater, and reducing energy consumption and equipment complexity.

CN117185390BActive Publication Date: 2026-06-30SUZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SUZHOU UNIV
Filing Date
2023-09-05
Publication Date
2026-06-30

AI Technical Summary

Technical Problem

In existing technologies, the hydrophobicity of conventional metal packings during the separation of tritium-containing wastewater results in a small gas-liquid contact area, affecting separation efficiency. Furthermore, traditional water distillation methods are energy-intensive, involve complex equipment, and pose safety hazards.

Method used

By modifying the metal wire mesh packing and loading it with metal-organic frameworks (MOFs), the hydrophilicity and mass transfer efficiency of the packing are improved, and the separation effect is enhanced by utilizing the isotope exchange effect.

Benefits of technology

It significantly improves the separation efficiency of tritium-containing wastewater, reduces purification energy consumption, enhances safety, and simplifies equipment structure.

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Abstract

This invention discloses a distillation packing material for treating tritium-containing wastewater and its preparation method. The method includes the steps of cleaning and drying a metal wire mesh packing material in an ultrasonic cleaner to obtain packing material A; immersing packing material A in a dilute HNO3 solution for corrosion modification to obtain packing material B; mixing a metal salt and an organic ligand in a solvent to obtain a loading solution C; and adding packing material B to the loading solution C and heating it in a high-pressure-Telflon reactor in a muffle furnace to obtain distillation packing material X. The distillation packing material of this invention, by modifying the metal packing material to improve its hydrophilicity, can better adsorb and retain water molecules, allowing them to be better distributed and flowed within the column, which is beneficial for improving mass and heat transfer efficiency. Furthermore, loading metal-organic framework materials (MOFs) capable of exchanging with hydrogen isotopes onto the modified metal packing material improves the separation and purification effect during the distillation process of treating tritium-containing wastewater.
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