一种含硫多功能聚乳酸材料及其制备方法

By polymerizing elemental sulfur with enols and lactide through a reverse sulfurization reaction, polylactic acid (PLA) materials with UV shielding and self-healing properties are synthesized, solving the problems of brittleness and UV sensitivity of PLA materials and enabling wider applications.

CN117186372BActive Publication Date: 2026-07-17NORTHWEST NORMAL UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NORTHWEST NORMAL UNIVERSITY
Filing Date
2023-09-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Polylactic acid (PLA) materials are brittle, have low ductility, are sensitive to ultraviolet light, and their hydrophobicity leads to biofouling, which limits their use in various applications.

Method used

Polylactic acid (PLA) materials with UV shielding, self-healing, and antibacterial properties are synthesized by polymerizing elemental sulfur with enols and lactide through a reverse sulfurization reaction. The dynamic SS bonds of sulfur absorb ultraviolet light and endow the material with self-healing properties. Enols and stannous octoate catalyst are added for polymerization.

Benefits of technology

It improves the UV shielding and self-healing properties of polylactic acid materials, enhances their antibacterial properties, and expands their application in packaging materials and other fields.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种含硫多功能聚乳酸材料及其制备方法,首先利用单质硫和十一烯醇(UnOH)、司盘80(Span 80)分别进行共聚合反应,得到逆硫化聚合物作为大分子引发剂,引发与丙交酯(LA)接枝共聚合反应,制备得到含硫聚乳酸材料。所得含硫聚乳酸材料具有良好的紫外屏蔽性能,自愈合性能和抗菌性能等。本发明方法操作简单,所得含硫聚乳酸材料具有多功能性,有效拓展聚乳酸材料的应用。
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