By forming an alumina protective film in a specific area of ​​the roller hearth furnace, the problem of the reaction between the raw materials of lithium-ion battery cathode components and the roller at high temperatures was solved, resulting in cost reduction and lifespan extension.

CN117248174BActive Publication Date: 2026-07-17COORSTEK GK

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
COORSTEK GK
Filing Date
2023-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The protective film of the existing roller hearth furnace rollers reacts with the raw materials of lithium-ion battery positive electrode components at high temperatures, causing the reactant blocks to detach, forming pits, increasing manufacturing costs and reducing the service life of the rollers. Moreover, the existing technology has not effectively solved the reaction problem of lithium-ion battery raw materials within the heat treatment temperature range.

Method used

A protective film of alumina is formed in a specific area of ​​the roller, with a thickness of more than 70 μm and less than 250 μm, and a C/L ratio of 0.33≦C/L≦0.8, to avoid full-length surface coverage. Combined with a mullite or zirconium oxide intermediate layer, the risk of reaction and cracking is reduced.

Benefits of technology

It effectively inhibits the reaction between the roller substrate and the metal elements of the workpiece, reduces manufacturing costs, extends the service life of the roller, and reduces cracking and peeling of the protective film.

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Abstract

提供一种辊底炉用的辊,其能够使制造成本进一步下降,且能够抑制辊基材与被烧制物所包含的金属元素的反应,能够抑制热喷涂膜的龟裂、剥落。本发明的辊是具有碳化硅材质的基材和覆盖前述基材的外表面的保护膜并合适地作为锂离子电池正极件原料的烧制用而使用的辊底炉用的辊,当将前述基材的相对于全长的在轴向方向上的中心作为(M)、将前述中心(M)直到前述辊的末端的距离作为(L)、将以前述中心(M)为基准而沿着前述轴向方向等量且相互反向的距离(C)所包含的前述基材的整个表面的区域作为(X)时,前述保护膜仅形成于前述区域(X),且0.33≦C / L≦0.8,前述保护膜的厚度是70μm以上250μm以下。
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