一种单脂环二酰胺受阻酚类抗氧剂及其制备方法

By preparing a mono-alicyclic diamide hindered phenolic antioxidant, the problem of poor performance of existing hindered phenolic antioxidants when used alone was solved, and the material properties were improved, especially the thermal stability, micro-aggregation and rheological properties.

CN117263821BActive Publication Date: 2026-07-17XIHUA UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XIHUA UNIV
Filing Date
2023-09-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing hindered phenolic antioxidants are ineffective when used alone, and their combined use affects material properties. They also lack the ability to improve the thermal properties, micro-aggregation properties, and rheological properties of materials.

Method used

A novel phenolic antioxidant with hindered monoalicyclic diamide was synthesized via a nucleophilic addition-elimination reaction. A specific monoalicyclic diamine and 3-(3,5-alkyl-4-hydroxyphenyl)propionate were used to form an antioxidant with amide bonds, thereby optimizing the material properties.

Benefits of technology

It improves the antioxidant properties of materials, enhances thermal stability, micro-aggregation and rheological properties, has a simple preparation method with high conversion rate, and the solvent can be recycled, making it highly competitive in the market.

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Abstract

本发明涉及有机合成和高分子材料领域,具体而言,涉及一种单脂环二酰胺受阻酚类抗氧剂及其制备方法。本发明的单脂环二酰胺受阻酚类抗氧剂的结构式如式I所示:其中G为如本发明说明书中结构式I‑1和I‑2所示的单脂环二胺结构,R和R'各自独立地选自甲基、乙基、异丙基或叔丁基。本发明的单脂环二酰胺受阻酚类抗氧剂不仅具有优良的抗氧化性能,而且具有改善材料热性能、微观聚集性能、流变性能等功能,应用价值更大;本发明提供的单脂环二酰胺受阻酚类抗氧剂的制备方法,工艺简单、单脂环二胺转化率高、过量3‑(3,5‑烷基‑4‑羟基苯基)丙酸酯和溶剂均可回收套用,市场竞争力强。
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