一种硫化铜矿石的浸出方法

By combining acidophilic iron-sulfur oxidizing microorganisms with chemical passivation layer removal agents, and using a microbial contact oxidation pond to treat copper sulfide ore, the limitation of the passivation layer on leaching efficiency was solved, and efficient copper mineral leaching was achieved.

CN117265264BActive Publication Date: 2026-07-17INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES
Filing Date
2023-11-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the leaching efficiency of copper sulfide ore is insufficient due to the formation of a passivation layer. Existing methods cannot effectively control or remove the passivation layer, which limits the oxidation rate and leaching rate of copper minerals.

Method used

Acidophilic iron-sulfur oxidizing microorganisms combined with chemical passivation layer removal agents were used to treat copper sulfide ore through microbial leaching extract and passivation layer removal agents. Subsequently, contact oxidation was carried out in a microbial contact oxidation tank. Adsorption materials were used to adsorb microorganisms and sulfur intermediate products to achieve the removal and oxidation of the passivation layer.

Benefits of technology

It significantly improved the oxidation rate and leaching rate of copper minerals, with a copper leaching rate of up to 85.5%. The leaching effect of copper sulfide ore was enhanced through a combination of chemical and biological methods.

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Abstract

本发明提供了一种硫化铜矿石的浸出方法,所述浸出方法包括如下步骤:采用微生物浸出提取液对硫化铜矿石浸出,所述微生物浸出提取液为含嗜酸铁硫氧化微生物的酸性三价铁溶液,得到微生物浸出体系;将钝化层脱除剂与所得浸出体系混合,脱除铜矿物表面硫中间产物钝化层,进入溶液;将所得浸出溶液进行微生物接触氧化,得到铜浸出液。本发明提供的硫化铜矿石的浸出方法通过化学脱除剂消除钝化层对浸出的阻碍,显著提升铜矿物氧化速率;同时采用微生物接触氧化池实现微生物数量及活性强化,在浸出反应体系外实现高效氧化溶液中的硫及亚铁,并再生浸出剂;微生物在整个反应体系循环,显著加速矿石及溶液中硫中间产物及亚铁氧化速率。
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