一种硅嵌入氮掺杂碳纳米片-三维石墨烯复合材料及其制备方法和应用

By preparing silicon-embedded nitrogen-doped carbon nanosheet anode materials on a three-dimensional graphene foam nickel substrate, the problems of volume expansion and poor conductivity of silicon anode materials in lithium-ion batteries were solved, and high-efficiency electrochemical performance was achieved.

CN117276478BActive Publication Date: 2026-07-17HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HEFEI GUOXUAN KEHONG NEW ENERGY TECH CO LTD
Filing Date
2023-09-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Silicon anode materials have low cycle reversibility in lithium-ion batteries due to volume expansion, poor conductivity, and active material shedding, which limits their practical application.

Method used

Using nickel foam loaded with three-dimensional graphene as a substrate, a silicon-embedded nitrogen-doped carbon nanosheet anode material was prepared. By embedding silicon nanoparticles in a three-dimensional graphene network and combining them with porous nitrogen-doped carbon nanosheets, a Si-NC/3DGN composite material was formed, which was directly used as an anode for lithium-ion batteries.

Benefits of technology

It effectively suppresses the volume expansion of silicon particles, improves conductivity and cycle stability, prevents active material shedding, and enhances battery performance.

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Abstract

本发明公开了一种硅嵌入氮掺杂碳纳米片‑三维石墨烯复合材料及其制备方法和应用,该材料的制备方法为:以负载有三维石墨烯(3DGN)的泡沫镍为基板,配制Si@MOF前驱体溶液后,将Si@MOF直接生长在3DGN上,然后通过碳化合成硅纳米颗粒嵌入氮掺杂碳纳米片,将硅纳米颗粒嵌入二维碳质结构中,可提高电荷传输路径,维持电荷扩散速率,进一步增强硅材料的导电性;其次,3DGN网络能促进电解质的渗透,保证锂离子快速扩散且缩短离子扩散距离,通过各组分协同作用,能够很好的制约硅基负极材料在充放电过程中的体积膨胀。此外,本发明中泡沫镍发挥集流体的作用,使所获得的材料能够直接作为负极应用在电池中,适合产业化应用。
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