一种氮掺杂碳量子点修饰的磷化亚铜 / 气相生长碳纤维复合材料的制备方法

By introducing copper into the surface of nitrogen-doped carbon quantum dots to prepare cuprous phosphide/vapor-grown carbon fiber composite materials, the conductivity and stability problems of sodium-ion battery anode materials are solved, achieving high capacity and low-temperature performance, which is suitable for industrial applications of sodium-ion batteries.

CN117276506BActive Publication Date: 2026-07-17SHANGHAI UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANGHAI UNIV
Filing Date
2023-09-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing sodium-ion battery anode materials, such as hard carbon, suffer from low tap density, temperature sensitivity, and sodium dendrite problems. Traditional Cu3P anode materials have poor conductivity, large volume expansion effect, and poor cycle performance, which limits their application in large-scale energy storage and low-temperature environments.

Method used

A nitrogen-doped carbon quantum dot-modified cuprous phosphide/vapor-grown carbon fiber composite material was prepared by introducing copper into the surface of nitrogen-doped carbon quantum dots in a one-step hydrothermal method. This method enhances conductivity and stability, avoids environmental pollution during phosphating, and achieves high specific capacity and low-temperature performance.

Benefits of technology

The prepared material exhibits excellent capacity and cycle stability at high rates, possesses low-temperature performance, is suitable for extreme weather conditions, and is suitable for the industrial production and practical application of sodium-ion batteries.

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Abstract

本发明公开了一种氮掺杂碳量子点修饰的磷化亚铜 / 气相生长碳纤维复合材料的制备方法,通过一步水热法在氮掺杂碳量子点表面引入铜元素并通过液相磷化合成高磷化亚铜负载量气相生长碳纤维支撑的复合材料,本发明提供的方法可减小磷化亚铜纳米颗粒的尺寸并增加其分散性,氮掺杂碳量子点的引入在实现高磷化亚铜负载量的同时提升了其容量并实现了活性材料和导电碳纤维的紧密结合,增强了倍率性能、稳定性和低温性能;该方法还可以避免磷化过程中使用过量磷化氢气体导致的环境污染,同时制备过程简单、易于控制、工艺重复性好、产品质量稳定,该电极材料兼具优异的低温性能,可应用于极端天气条件,对实现钠离子电池的工业化生产和实际应用具有深远意义。
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