一种高效率热电半导体PN结及其应用

By doping carbon nanoparticles and elements such as antimony, gallium, and magnesium into bismuth telluride-based semiconductors, and using fused deposition modeling (FDM) 3D printing technology to form a high-efficiency thermoelectric PN junction, the problems of low thermoelectric conversion efficiency and poor thermal stability of bismuth telluride semiconductor cooling chips are solved, achieving efficient cooling and good heat dissipation.

CN117279470BActive Publication Date: 2026-07-17INST OF WENZHOU ZHEJIANG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INST OF WENZHOU ZHEJIANG UNIV
Filing Date
2023-09-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing bismuth telluride semiconductor refrigeration chips have low thermoelectric conversion efficiency and poor thermal stability, making it difficult to meet the demand for high-efficiency refrigeration.

Method used

A high-efficiency thermoelectric semiconductor PN junction is formed by layer-by-layer printing of nanoscale P-type and N-type semiconductor powders at 300-400℃ using a fused deposition modeling (FDM) printer. By doping carbon nanoparticles and antimony into the P-type semiconductor and gallium and magnesium into the N-type semiconductor, the material composition is optimized to improve electrical conductivity and reduce thermal conductivity.

Benefits of technology

It achieves a cooling efficiency of up to 92% and good thermal stability, significantly improving the performance of thermoelectric materials and reducing costs.

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Abstract

本发明涉及一种高效率热电半导体PN结及其应用,将纳米级P型半导体粉体和纳米级N型半导体粉体经熔融沉积3D打印机在300~400℃的温度下熔融挤出后,逐层打印形成所述高效率热电半导体PN结,所述P型半导体的化学式为Xa / Bi2‑b‑cGabSbcTe3,其中X为改性材料,X选自石墨烯、碳纳米管、碳纳米颗粒中的至少一种;a为改性材料X在P型半导体中的质量分数,0.2%≤a≤0.4%;b为掺杂元素镓的化学计量比,0.29≤b≤0.35;所述N型半导体的化学式为Yd / Bi2Te3‑d‑eSee,其中Y为掺杂元素,Y选自镓、镁、钠、铜、铬的至少一种。通过在P型半导体和N型半导体的基材碲化铋中掺杂锑、硒提高了热电材料的电性能、热传导性能,改善其热稳定性,使其散热效果好、制冷效率高,而且降低了成本。
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