低介电线性聚磷腈阻燃剂及其在双马来酰亚胺复合材料制备中的应用

By introducing linear polyphosphazene flame retardant into bismaleimide resin, the problems of brittleness and insufficient dielectric properties are solved, and a composite material with high impact strength, low dielectric constant and excellent flame retardant properties is realized, which is suitable for 5G electronic packaging materials.

CN117327286BActive Publication Date: 2026-07-17UNIV OF SCI & TECH OF CHINA

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
UNIV OF SCI & TECH OF CHINA
Filing Date
2023-11-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Bismaleimide resins suffer from brittleness and poor processing characteristics, and their dielectric properties are insufficient to meet the requirements of 5G electronic packaging materials. In addition, the introduction of existing toughening agents reduces fire safety.

Method used

By using linear polyphosphazene flame retardant as a modifier, and blending it with bismaleimide prepolymer, a low dielectric, flame retardant and toughened composite material was prepared. The halogen-free, elastomer properties and reactive double bonds of linear polyphosphazene were utilized to improve interfacial compatibility and dielectric properties.

Benefits of technology

It significantly improves the impact strength and flame retardant properties of bismaleimide composite materials, reduces the dielectric constant, meets the dielectric performance requirements of 5G electronic packaging materials, and maintains good thermal stability and environmental friendliness.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种低介电线性聚磷腈阻燃剂及其在双马来酰亚胺复合材料制备中的应用。本发明线性聚磷腈阻燃剂的结构如下式Ⅰ所示:其中R为含端羟基的降冰片烯类脂肪族立体环状化合物,n的范围为2~20。本发明制备的线性聚磷腈阻燃剂具有热稳定性好,介电性能优异,自熄性等特点;并且由其制备的双马来酰亚胺复合材料的综合性能优异,仅仅添加1wt%该阻燃剂就可使双马来酰亚胺复合材料的UL‑94达到V0级别,冲击韧性提高50%~100%,介电常数降低至2.5~3.0。
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