A rheological agent and a preparation method thereof, daily chemical products

Abstract

The application is suitable for the technical field of chemical materials, and provides a rheological agent, a preparation method thereof and daily chemical products.The rheological agent comprises the following raw materials in mass fractions: organic bentonite 1-10 parts, sulfonic acid 10-30 parts, PVA 1-8 parts, non-ionic surfactant 10-30 parts, sodium hydroxide 0.1-1 part, polyglycerol ester 1-10 parts and water 35-50 parts.The rheological agent obtained by compounding the organic bentonite, the sulfonic acid, the PVA, the non-ionic surfactant, the sodium hydroxide and the polyglycerol ester in a specific mass ratio is applied to the daily chemical products, so that the rheological properties of the daily chemical products can be improved, the storage stability of the daily chemical products can be improved, the decontamination and the recycling washing performance of the obtained daily chemical products are high, the obtained daily chemical products have the effect of suspending perfume and are friendly to human bodies and non-irritating.In addition, the raw materials used in the application are simple and easy to obtain, the preparation process is simple, green, pollution-free and can be quickly industrialized.

Description

Technical Field

[0001] This application belongs to the field of chemical materials technology, and in particular relates to a rheology modifier and its preparation method, as well as daily chemical products. Background Technology

[0002] Rheology modifiers are a class of raw materials used in multi-component liquid and semi-liquid products. They are substances that can increase the viscosity of a product and change its rheological properties, giving the product characteristics such as high yield stress and high thixotropic index, and achieving properties such as product storage stability, anti-settling, and anti-sagging.

[0003] Rheology modifiers can be divided into two categories: natural and synthetic. Natural rheology modifiers are mainly derived from plants and seaweed, such as carrageenan, xanthan gum, and alginic acid. These substances can form stable emulsions and gels in cosmetics, while also providing moisturizing and antioxidant effects. Due to the limited availability and high cost of natural rheology modifiers, most daily chemical product manufacturers choose to use synthetic thickening rheology modifiers. There are many types of synthetic rheology modifiers, including hydroxyethyl cellulose, polyacrylamide, and polysorbate. While these substances are less expensive, their stability and viscosity adjustment capabilities need improvement. Furthermore, some synthetic rheology modifiers may irritate the human body and generate large amounts of waste gas and wastewater during the synthesis process, which is detrimental to environmental protection.

[0004] It is evident that existing synthetic rheology modifiers have issues such as insufficient stability and viscosity adjustment capabilities, high irritation to the human body, significant environmental pollution, and unfavorable conditions for industrialization. Summary of the Invention

[0005] The purpose of this application is to provide a rheology modifier that addresses the problems of existing synthetic rheology modifiers, such as insufficient stability and viscosity adjustment capabilities, high irritation to the human body, significant environmental pollution, and unfavorable conditions for industrialization.

[0006] The embodiments of this application are implemented as follows: a rheology modifier comprises the following raw materials in parts by mass:

[0007] The ingredients are: 1-10 parts organic bentonite, 10-30 parts sulfonic acid, 1-8 parts PVA, 10-30 parts nonionic surfactant, 0.1-1 parts sodium hydroxide, 1-10 parts polyglycerol ester, and 35-50 parts water.

[0008] Another objective of this application is a method for preparing a rheology modifier, comprising:

[0009] Weigh the raw materials according to the above rheology modifier formula and set aside;

[0010] Organic bentonite was placed in water and subjected to ultrasonic treatment to obtain a bentonite dispersion.

[0011] Sulfonic acid and sodium hydroxide were added to the bentonite dispersion and the mixture was stirred to obtain a first mixture.

[0012] At a temperature of 80℃-90℃, PVA and polyglycerol ester are added to the first mixture and stirred for 50-70 minutes. The mixture is then cooled to 65-75℃ and stirred for another 50-70 minutes. A nonionic surfactant is added and stirred for another 110-130 minutes. After cooling, the rheology modifier is obtained.

[0013] Another objective of this application is to provide a daily chemical product, which includes the aforementioned rheology modifier.

[0014] The rheology modifier provided in this application is prepared by compounding organic bentonite, sulfonic acid, PVA, nonionic surfactant, sodium hydroxide, and polyglycerol ester in a specific mass ratio. When applied to daily chemical products, it can improve the rheological properties of these products, increase their viscosity, enhance storage stability, and result in products with high detergency and recycle performance. Furthermore, it possesses the effect of suspending fragrance and is human-friendly and non-irritating. In addition, the raw materials used in this rheology modifier are simple and readily available, the preparation process is simple, green, and pollution-free, and can be rapidly industrialized. Detailed Implementation

[0015] To make the objectives, technical solutions, and advantages of this application clearer, the following detailed description is provided in conjunction with embodiments. It should be understood that the specific embodiments described herein are merely illustrative and not intended to limit the scope of this application.

[0016] This application addresses the problems of existing synthetic rheology modifiers, such as insufficient stability and viscosity adjustment capabilities, high irritation to humans, significant environmental pollution, and hindering industrialization. It provides a rheology modifier prepared by compounding organic bentonite, sulfonic acid, PVA, nonionic surfactant, sodium hydroxide, and polyglycerol ester in a specific mass ratio. When applied to daily chemical products, it improves the rheological properties of these products, increases their viscosity, enhances storage stability, and results in products with high detergency and recycle performance. Furthermore, it provides the effect of suspending fragrances and is human-friendly and non-irritating. In addition, the raw materials used in this rheology modifier are simple and readily available, the preparation process is simple, environmentally friendly, and can be rapidly industrialized.

[0017] Specifically, this application provides a rheology modifier comprising the following parts by weight of raw materials:

[0018] 1-10 parts organic bentonite, 10-30 parts sulfonic acid, 1-8 parts PVA, 10-30 parts nonionic surfactant, 0.1-1 parts sodium hydroxide, 1-10 parts polyglycerol ester, and 35-50 parts water.

[0019] In the embodiments of this application, the organobentonite is a white to light yellow flowable powder, more preferably a white flowable powder. Preferably, the particle size (through 400 mesh) of the organobentonite is >90%, more preferably >95%. The finer and more uniform the particle size of the organobentonite, the better the storage stability of the corresponding rheology modifier at the same addition amount.

[0020] In the embodiments of this application, the specific gravity of the organic bentonite should not be too high, otherwise it will lead to a decrease in the yield stress of the obtained rheology modifier and poor rheological effect. Based on the research in this application, the specific gravity (25℃) of the organic bentonite is determined to be ≤2.7 g / cm³. 3 More preferably ≤2.6g / cm 3 The lower the specific gravity of organic bentonite, the higher the yield stress of the rheology modifier and the better the rheological effect for the same amount of addition.

[0021] In the embodiments of this application, if the molecular weight of PVA is too large, it will be difficult to dissolve, and the viscosity of the rheology modifier will increase, affecting the application of the rheology modifier. However, if the molecular weight is too small, the rheological effect of the rheology modifier will be reduced. Based on the research determined in this application, the molecular weight of the PVA (M...) is... W It should be controlled between 80,000 and 150,000.

[0022] In the embodiments of this application, the nonionic surfactant is at least one of fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty acid polyoxyethylene ester, polyoxyethylene alkylamine, and polyoxyethylene alkylamide.

[0023] In the embodiments of this application, the polyglycerol ester is at least one of triglyceride monostearate, tetraglyceride monolaurate, tetraglyceride laurate, diglyceride stearate, and triglyceride myristate.

[0024] In a preferred embodiment of this application, the rheology modifier comprises the following raw materials in parts by weight:

[0025] 5 parts organic bentonite, 20 parts sulfonic acid, 8 parts PVA, 20 parts nonionic surfactant, 0.59 parts sodium hydroxide, 5 parts polyglycerol ester, and 45.41 parts water.

[0026] This application also provides a method for preparing a rheology modifier, comprising:

[0027] Weigh the raw materials according to the above rheology modifier formula and set aside;

[0028] Organic bentonite was placed in water and subjected to ultrasonic treatment to obtain a bentonite dispersion.

[0029] Sulfonic acid and sodium hydroxide were added to the bentonite dispersion and the mixture was stirred to obtain a first mixture.

[0030] At a temperature of 80℃-90℃, PVA and polyglycerol ester are added to the first mixture and stirred for 50-70 minutes. The mixture is then cooled to 65-75℃ and stirred for another 50-70 minutes. A nonionic surfactant is added and stirred for another 110-130 minutes. After cooling, the rheology modifier is obtained.

[0031] In this process, bentonite and water are first ultrasonically treated to facilitate the formation of a three-dimensional cascade structure in the bentonite, resulting in a suspension effect in the product. This allows it to be used in daily chemical products as a suspended fragrance. The addition of sulfonic acid and sodium hydroxide promotes their uniform mixing. If PVA and polyglycerol ester are added first, the increased viscosity of the system would easily lead to uneven mixing of sulfonic acid and sodium hydroxide. Adding PVA and polyglycerol ester at a temperature of 80-90℃ takes into account the solubility of PVA and the viscosity of the system. Finally, the surfactant is added because surfactants tend to foam, and adding them first would hinder production.

[0032] This application also provides a daily chemical product, which includes the above-mentioned rheology modifier. The daily chemical product includes at least one of laundry detergent and laundry pods. The preparation of the daily chemical product can employ existing mature formulations and preparation methods. For example, it can be obtained by adding sodium linear alkylbenzene sulfonate, sodium fatty alcohol polyoxyethylene ether sulfate, and ammonium fatty alcohol polyoxyethylene ether sulfate to water at a temperature of 40-45°C, stirring, then heating to 60°C and adding sodium citrate and citric acid, stirring, then cooling to 45°C and adding NaCl, the above-mentioned rheology modifier, and fragrance, and stirring.

[0033] The following are embodiments of some implementations of this application, which are not intended to limit the scope of this application.

[0034] Furthermore, it should be noted that all materials and processing methods appearing in this application, unless otherwise stated, are common materials and familiar technical means in the art. The numerical values ​​given in the following embodiments are as accurate as possible; however, those skilled in the art will understand that due to unavoidable measurement errors and experimental operation problems, each number should be understood as an approximation rather than an absolutely accurate value.

[0035] Example 1

[0036] Weigh 1g, the specific gravity is 2.6g / cm³. 3Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 49.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 80000) and 1g of triglyceride stearate were added and stirred for 60min. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0037] Example 2

[0038] Weigh 5g, the specific gravity is 2.5g / cm³. 3 Organobentonite with a particle size (passing through 400 mesh) > 95% was ultrasonicated in 45.41g of water at room temperature for 60min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 20g of sulfonic acid was weighed and added to the flask. 0.59g of sodium hydroxide was added for neutralization. The temperature was raised to 90℃, and 8g of PVA (Mw = 120000) and 5g of diglycerol isostearate were added, and the mixture was stirred for 60 minutes. The temperature was lowered to 70℃, and the mixture was stirred for 1 hour. 20g of alkylphenol polyoxyethylene ether was added, and the mixture was stirred for another 2 hours. Under stirring, the mixture was cooled to 45℃ and discharged to obtain a rheology modifier.

[0039] Example 3

[0040] Weigh 10g, the specific gravity is 2.4g / cm³. 3 Organobentonite with a particle size (passing through 400 mesh) > 98% was ultrasonicated in 38.9g of water at room temperature for 90min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 30g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 90℃, and 1g of PVA (Mw = 150000) and 5g of triglyceride laurate were added, and the mixture was stirred for 60 minutes. The temperature was lowered to 70℃, and the mixture was stirred for 1 hour. 10g of fatty acid polyoxyethylene ester was added, and the mixture was stirred for another 2 hours. Under stirring, the temperature was lowered to 45℃ and the mixture was discharged to obtain a rheology modifier.

[0041] Comparative Example 1

[0042] The difference between this comparative example and Experimental Example 1 is that the ultrasonic dispersion of bentonite in water is replaced by stirring dispersion. The specific process is as follows:

[0043] Weigh 1g, the specific gravity is 2.6g / cm³. 3Organic bentonite with a particle size (passing through 400 mesh) > 90% was stirred in 49.82g of water at room temperature for 30 minutes to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 80000) and 1g of triglyceride stearate were added and stirred for 60 minutes. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirred for another 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain a rheology modifier.

[0044] Comparative Example 2

[0045] The difference between this comparative example and Experimental Example 1 is that the bentonite was replaced with bentonite with a higher specific gravity. The specific process is as follows:

[0046] Weigh 1g, the specific gravity is 2.8g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 49.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 80000) and 1g of triglyceride stearate were added and stirred for 60min. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring was continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0047] Comparative Example 3

[0048] The difference between this comparative example and Experimental Example 1 is that the bentonite was replaced with bentonite with a larger particle size. The specific process is as follows:

[0049] Weigh 1g, the specific gravity is 2.8g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) <80% was ultrasonicated in 49.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA and 1g of triglyceride stearate were added and stirred for 60min. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring was continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0050] Comparative Example 4

[0051] The difference between this comparative example and Experimental Example 1 is that it uses PVA with a larger molecular weight. The specific process is as follows:

[0052] Weigh 1g, the specific gravity is 2.6g / cm³.3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 49.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 200000) and 1g of triglyceride stearate were added and stirred for 60 minutes. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring was continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0053] Comparative Example 5

[0054] The difference between this comparative example and Experimental Example 1 is that it uses PVA with a smaller molecular weight. The specific process is as follows:

[0055] Weigh 1g, the specific gravity is 2.6g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 49.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 60000) and 1g of triglyceride stearate were added and stirred for 60min. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring was continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0056] Comparative Example 6

[0057] The difference between this comparative example and Experimental Example 1 is that the number of PVA samples used is increased. The specific process is as follows:

[0058] Weigh 1g, the specific gravity is 2.6g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 42.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 15g of PVA (Mw = 80000) and 1g of triglyceride stearate were added and stirred for 60 minutes. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring was continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0059] Comparative Example 7

[0060] The difference between this comparative example and Experimental Example 1 is that the amount of bentonite used is increased and the amount of PVA used is decreased. The specific process is as follows:

[0061] Weigh 20g, the specific gravity is 2.6g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 42.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 1g of PVA (Mw = 80000) and 1g of triglyceride stearate were added and stirred for 60min. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0062] Comparative Example 8

[0063] The difference between this comparative example and Experimental Example 1 is that the amount of fatty alcohol polyoxyethylene ether used is reduced. The specific process is as follows:

[0064] Weigh 1g, the specific gravity is 2.6g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 74.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 80000) and 1g of triglyceride stearate were added and stirred for 60 minutes. The temperature was lowered to 70℃ and stirred for 1 hour. 5g of fatty alcohol polyoxyethylene ether was added and stirring was continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0065] Comparative Example 9

[0066] The difference between this comparative example and Experimental Example 1 is that the amount of fatty alcohol polyoxyethylene ether used is increased, and the specific process is as follows:

[0067] Weigh 1g, the specific gravity is 2.6g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 34.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 80000) and 1g of triglyceride stearate were added and stirred for 60min. The temperature was lowered to 70℃ and stirred for 1 hour. 45g of fatty alcohol polyoxyethylene ether was added and stirring continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0068] Comparative Example 10

[0069] The difference between this comparative example and Experimental Example 1 is that triglyceride stearate was not used. The specific procedure is as follows:

[0070] Weigh 1g, the specific gravity is 2.6g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 69.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500ml flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 80000) was added and stirred for 60min. The temperature was lowered to 70℃, and the mixture was stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added, and the mixture was stirred for another 2 hours. Under stirring, the temperature was lowered to 45℃ and the mixture was discharged to obtain the rheology modifier.

[0071] Comparative Example 11

[0072] The difference between this comparative example and Experimental Example 1 is that the amount of triglyceride stearate used is increased, as detailed below:

[0073] Weigh 1g, the specific gravity is 2.6g / cm³. 3 Organic bentonite with a particle size (passing through 400 mesh) > 90% was ultrasonicated in 49.82g of water at room temperature for 30min to obtain a bentonite dispersion. The dispersion was poured into a 500mL flask and stirred continuously. 10g of sulfonic acid was weighed and added to the flask. 0.1g of sodium hydroxide was added for neutralization. The temperature was raised to 80℃, and 8g of PVA (Mw = 80000) and 20g of triglyceride stearate were added and stirred for 60min. The temperature was lowered to 70℃ and stirred for 1 hour. 30g of fatty alcohol polyoxyethylene ether was added and stirring was continued for 2 hours. Under stirring, the temperature was lowered to 45℃ and the product was discharged to obtain the rheology modifier.

[0074] The rheology modifiers prepared in Examples 1-3 and Comparative Examples 1-11 were applied to the preparation of detergent compositions. Specifically, 25g of deionized water was weighed into a beaker and heated to 40-45°C with stirring. 35g of sodium linear alkylbenzene sulfonate (LAS), 5g of sodium fatty alcohol polyoxyethylene ether sulfate (AES), and 5g of ammonium fatty alcohol polyoxyethylene ether sulfate (AESA) were added, and the mixture was stirred for 5 minutes. The system was then heated to 60°C and homogenized at 2000 rpm for 3 minutes. 3.5g of sodium citrate and 0.1g of citric acid were added, and the mixture was stirred for 30 seconds. The temperature was then lowered to 45°C while stirring. 0.5g of NaCl, 2g of the rheology modifiers prepared in the above examples or comparative examples, and 0.1g of microcapsule fragrance were added, and the mixture was stirred for 10 minutes to obtain the detergent composition.

[0075] Stability tests were conducted on the detergent compositions prepared using the rheology modifiers in Examples 1-3 and Comparative Examples 1-11. High-temperature storage stability: After sealing the bottle, the composition was placed in an environment of 50℃±1℃ for 4 weeks, then returned to room temperature (25℃±5℃). No stratification or precipitation was observed, indicating satisfactory high-temperature stability. Low-temperature stability: After sealing the bottle, the composition was placed in an environment of 0℃±2℃ for 4 weeks, then immediately observed. No stratification or precipitation was observed, indicating satisfactory low-temperature stability. Freeze-thaw cycle stability: After being placed in an environment of -15℃ to -20℃ for 24 hours, then placed in an environment of room temperature (25℃±5℃) for 24 hours, this constituted one cycle. Four consecutive cycles were performed, with observation of the composition's state after each cycle. No stratification or precipitation was observed, indicating satisfactory freeze-thaw cycle stability. Room temperature stability: After sealing the bottle, the composition was placed in a room temperature environment (20℃-30℃) for 4 weeks. No stratification or precipitation was observed, indicating satisfactory room temperature stability. The test results are shown in Table 1.

[0076] Table 1 Storage stability of detergent compositions

[0077]

[0078]

[0079] The detergent compositions prepared using the rheology modifiers in Examples 1-3 and Comparative Examples 1-11 were tested for their washing performance. The detergency was determined according to GB / T 13174-2008, "Determination of detergency and recycle performance of detergents for clothing," with a sample concentration of 0.1%. The test results are shown in Table 2.

[0080] Table 2. Results of Decontamination Performance Test

[0081] Example 1 1.03 1.02 1.03 Example 2 1.03 1.02 1.02 Example 3 1.03 1.03 1.03 Comparative Example 1 1.10 1.09 1.11 Comparative Example 2 1.10 1.10 1.12 Comparative Example 3 1.09 1.10 1.09 Comparative Example 4 1.09 1.09 1.11 Comparative Example 5 1.09 1.10 1.12 Comparative Example 6 1.10 1.10 1.12 Comparative Example 7 1.10 1.11 1.12 Comparative Example 8 1.20 1.21 1.22 Comparative Example 9 1.03 1.02 1.01 Comparative Example 10 1.15 1.15 1.14 Comparative Example 11 1.08 1.07 1.07

[0082] The embodiments described above are merely illustrative of several implementation methods of this application, and while the descriptions are specific and detailed, they should not be construed as limiting the scope of this patent application. It should be noted that those skilled in the art can make various modifications and improvements without departing from the concept of this application, and these all fall within the protection scope of this application. Therefore, the protection scope of this patent application should be determined by the appended claims.

[0083] The above description is merely a preferred embodiment of this application and is not intended to limit this application. Any modifications, equivalent substitutions, and improvements made within the spirit and principles of this application should be included within the protection scope of this application.

Claims

1. A rheology modifier, characterized in that, The raw materials include the following parts by weight: 1-10 parts organic bentonite, 10-30 parts sulfonic acid, 1-8 parts PVA, 10-30 parts nonionic surfactant, 0.1-1 parts sodium hydroxide, 1-10 parts polyglycerol ester, and 35-50 parts water; the organic bentonite has a particle size greater than 90% that is 400 mesh; the organic bentonite has a specific gravity of ≤2.7 g / cm³ at 25°C; the PVA has a weight-average molecular weight of 80,000-150,000; the organic bentonite is processed by ultrasonic treatment in water to obtain a bentonite dispersion.

2. The rheology modifier according to claim 1, characterized in that, The raw materials include the following parts by weight: 5 parts organic bentonite, 20 parts sulfonic acid, 8 parts PVA, 20 parts nonionic surfactant, 0.59 parts sodium hydroxide, 5 parts polyglycerol ester, and 45.41 parts water.

3. The rheology modifier according to claim 1, characterized in that, The nonionic surfactant is at least one of fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty acid polyoxyethylene ester, polyoxyethylene alkylamine, and polyoxyethylene alkylamide.

4. The rheology modifier according to claim 1, characterized in that, The polyglycerol ester is at least one of triglyceride monostearate, tetraglyceride lauryl ester, diglyceride stearate, and triglyceride myristate.

5. A method for preparing a rheology modifier, characterized in that, include: Weigh the raw materials according to the rheology modifier formulation of claim 1 and set aside; place the organic bentonite in water and sonicate to obtain a bentonite dispersion. Sulfonic acid and sodium hydroxide were added to the bentonite dispersion and stirred to obtain a first mixture. At a temperature of 80℃-90℃, PVA and polyglycerol ester are added to the first mixture and stirred for 50-70 minutes. The mixture is then cooled to 65-75℃ and stirred for another 50-70 minutes. A nonionic surfactant is added and stirred for another 110-130 minutes. After cooling, the rheology modifier is obtained.

6. A daily chemical product, characterized in that, The daily chemical products include the rheology modifier as described in claim 1.

7. The daily chemical product according to claim 6, characterized in that, The aforementioned daily chemical product is obtained by adding sodium linear alkylbenzene sulfonate, sodium fatty alcohol polyoxyethylene ether sulfate, and ammonium fatty alcohol polyoxyethylene ether sulfate to a water temperature of 40-45°C and stirring, then heating to 60°C and adding sodium citrate and citric acid and stirring, then cooling to 45°C and adding NaCl and the rheology modifier and fragrance as described in claim 1 and stirring.

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