双缺陷调控硫化铋光催化剂及制备方法和应用

By introducing anion and cation defects into bismuth sulfide photocatalysts, the problem of insufficient utilization of near-infrared light in existing technologies is solved, achieving efficient degradation of antibiotics under near-infrared light, broadening the spectral utilization range, and featuring a green and environmentally friendly preparation process.

CN117427658BActive Publication Date: 2026-07-17HUBEI NORMAL UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUBEI NORMAL UNIV
Filing Date
2023-09-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing semiconductor photocatalysts have difficulty effectively utilizing near-infrared light in the solar spectrum, which limits their application in treating microplastics in aquatic environments.

Method used

By introducing anion and cation defects into bismuth sulfide photocatalysts and treating them with sodium borohydride and sodium hydroxide, a dual-defect regulated bismuth sulfide photocatalyst was constructed, which broadened its near-infrared spectral absorption range and improved its photon absorption rate and the separation ability of photogenerated electron-hole pairs.

Benefits of technology

It achieves highly efficient degradation of antibiotics under near-infrared light, improves photocatalytic performance, broadens the spectral utilization range, and has a green and environmentally friendly preparation process.

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Abstract

本发明涉及一种双缺陷调控硫化铋光催化剂,将硫化铋光催化剂分散在超纯水中,再分别投加硼氢化钠及氢氧化钠,搅拌,得到黑色沉淀;对所得黑色沉淀物进行洗涤,再真空干燥,得到双缺陷调控硫化铋光催化剂。一种上述双缺陷调控硫化铋光催化剂在降解抗生素中的应用。有益效果为:将阴离子硫缺陷和阳离子铋缺陷同时引入硫化铋晶体中,利用缺陷工程可以重构催化剂的能带结构、拓宽近红外光谱吸收范围、提高光子吸收率,其次,所形成的缺陷能级可加快光生电子‑空穴对的分离和迁移,光催化剂的阴、阳离子缺陷会产生更多的自由电子,使得双缺陷调控硫化铋光催化剂具有优良的近红外光催化性能,对四环素具有高的降解能力。
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