一种光热复合膜及其制备方法

By mixing photothermal conversion materials with PVDF-based polymers and performing laser irradiation polarization treatment, regional crystallization is formed, which solves the problem of low β-phase crystal content in PVDF piezoelectric materials and realizes controllable thermal and electrical stimulation modulation, making it suitable for biomedical applications.

CN117511091BActive Publication Date: 2026-07-17INST OF WENZHOU ZHEJIANG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INST OF WENZHOU ZHEJIANG UNIV
Filing Date
2023-11-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the preparation process of existing PVDF piezoelectric materials, it is difficult to increase the β-phase crystal content, and the post-processing process damages the function of the composite material, making it impossible to achieve thermal and electrical stimulation regulation in specific regions.

Method used

By mixing photothermal conversion materials with PVDF-based polymers and then performing laser irradiation and polarization treatment, regional crystallization is formed, achieving controllable regional distribution of surface potential and photothermal effect.

Benefits of technology

The crystallization content and ferroelectric properties of the PVDF piezoelectric phase were improved, enabling controllable thermal and electrical stimulation in specific regions, which is suitable for precise regulation of cell behavior in the biomedical field.

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Abstract

本发明公开了一种光热复合膜及其制备方法。该光热复合膜是以PVDF基聚合物作为基体并将光热转换材料分散在所述基体中形成的,且所述光热复合膜的表面电势呈现为可控的区域化分布。通过调控激光的照射范围、强度和时间来控制结晶的区域、温度和时间,继而实现特定区域的结晶,最后通过电场极化使结晶部位产生可控表面电势和压电响应性,实现表面电势区域化调控。同时,通过调控光热转换材料的种类、含量以及激光照射时间实现可控的光热效应。因此,该光热复合膜兼具有光热效应和可控的区域化分布的表面电势,可用作施加热刺激和 / 或电刺激的生物材料。本发明制备方法工艺简单,易于实现,有利于进行推广应用。
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