一种硅基负极材料及其制备方法

By employing a double-layer coating structure on silicon-based anode materials, combined with a carbon coating layer generated from the pyrolysis of lithium fluoride and nanocellulose, the volume expansion and conductivity issues of silicon-based anode materials are solved, thereby improving the cycle performance and stability of the battery.

CN117525366BActive Publication Date: 2026-07-17龙子湖新能源实验室 +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
龙子湖新能源实验室
Filing Date
2023-12-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Silicon-based anode materials in lithium-ion batteries suffer from problems such as large volume expansion and poor conductivity after lithium intercalation, leading to material pulverization and continuous formation of SEI film, which affects the cycle life and performance of the battery.

Method used

The structure employs a double-layer coating: the inner layer is nano-silicon, the middle layer is a porous carbon framework doped with lithium fluoride, and the outer layer is a carbon coating layer generated by the pyrolysis of nanocellulose, forming a good conductive pathway. The stability of the SEI film is improved by lithium fluoride, and a dense outer carbon coating layer is formed by ionic liquid and cellulose.

Benefits of technology

It improves the conductivity and cycle performance of silicon-based anode materials, enhances the stability of the materials, and extends the battery's lifespan.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供了一种硅基负极材料及其制备方法。所述硅基负极材料为多层复合包覆结构,本发明得到的硅基负极材料以氟化锂掺杂的多孔碳为基体骨架,将高容量纳米硅颗粒沉积在氟化锂改性多孔碳内部,多孔碳在构建了强大导电网络的同时给硅颗粒提供了足够的膨胀空间,在材料中引入氟化锂,形成更加致密的SEI膜,以保证材料的稳定性;最外层的纤维素热解产物再次形成一个碳包覆层,使得所制备的硅碳负极材料具有较高容量,并且循环性能较好,且纤维素表面有大量的羟基可以与氟形成氢键,使包覆更加均匀致密,进一步增强材料的稳定性。
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