一种具有高度悬浮分散性能的氧化铝纳米管基酯交换催化剂及其制备方法和应用

Alumina nanotube-based transesterification catalysts were prepared by impregnating potassium oxide on the surface of alumina nanotubes. This solved the problems of easy precipitation and decreased activity of transesterification catalysts in the reaction solution, and enabled efficient transesterification reactions and catalyst reuse, thereby improving the activity and stability of the catalyst.

CN117563579BActive Publication Date: 2026-07-17YANGZHOU INST OF CHEM & CHEM ENG NANJING UNIV +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
YANGZHOU INST OF CHEM & CHEM ENG NANJING UNIV
Filing Date
2023-11-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing transesterification catalysts have poor solubility in reaction solutions, are prone to precipitation and scaling, and their activity decreases after repeated use, affecting catalyst life. They are also prone to clogging pipelines. Furthermore, traditional heterogeneous catalysts have poor thermal stability and low selectivity.

Method used

Using alumina nanotubes as a carrier, and by impregnating their surface with the active component potassium oxide, an alumina nanotube-based transesterification catalyst with high suspension and dispersion performance is prepared by utilizing the acid-base synergistic effect. This improves the catalyst's activity and dispersion effect, and achieves good contact between the catalyst and the reactants.

Benefits of technology

It improves the transesterification reaction rate, reduces the amount of catalyst used, extends the catalyst life, and the catalyst can be reused. It has a stable structure, is not easily lost due to trace amounts of moisture, and has good mass transfer effect and suspension dispersion performance.

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Abstract

本发明公开了一种具有高度悬浮分散性能的氧化铝纳米管基酯交换催化剂及其制备方法和应用,属于化工新材料技术领域。该方法将活性组分氧化钾溶液浸渍在氧化铝纳米管表面,烘干,焙烧,即获得氧化铝纳米管基酯交换催化剂。本发明制备的氧化铝纳米管基酯交换催化剂具有高度悬浮分散性能,用于碳酸二甲酯与乙醇进行酯交换反应生成碳酸甲乙酯与碳酸二乙酯中,催化时间短,可用于工业化大规模生产,具有良好的实用性。
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