一种高介电常数聚丙烯组合物及其制备方法和应用

By preparing dielectric reinforcing agents and reactive extrusion of macromolecular dielectric reinforcing agents with polypropylene resin, the problems of dielectric loss and breakdown strength decrease caused by the increase of dielectric constant were solved, and a polypropylene composition with high dielectric constant and low dielectric loss was realized, which is suitable for film capacitors and lithium battery separators.

CN117659285BActive Publication Date: 2026-07-17PETROCHINA CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PETROCHINA CO LTD
Filing Date
2022-08-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies often lead to increased dielectric loss and decreased breakdown strength in the process of improving the dielectric constant of polypropylene. At the same time, uneven dispersion of inorganic materials makes film processing difficult.

Method used

Dielectric enhancers were prepared by reacting aliphatic diisocyanates with polyols and alkoxysilanes, and macromolecular dielectric enhancers were prepared by combining nickel-based complexing catalysts and alkylaluminoxane co-catalysts. High dielectric constant polypropylene compositions were prepared by reactive extrusion with polypropylene resin.

Benefits of technology

While maintaining the excellent properties of polypropylene, it significantly improves the dielectric constant and reduces dielectric loss, making it suitable for thin film capacitors and lithium battery separators.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure BDA0003817966080000041
    Figure BDA0003817966080000041
  • Figure BDA0003817966080000141
    Figure BDA0003817966080000141
  • Figure BDA0003817966080000151
    Figure BDA0003817966080000151
Patent Text Reader

Abstract

本发明公开了一种高介电常数聚丙烯组合物及其制备方法和应用。本发明首先用烷氧基硅烷、二异氰酸酯类在多元醇的环境中合成出具有强极性基团的介电增强剂;其次在镍基络合催化剂的存在下由反应单体乙烯、介电增强剂制备出具有自由基反应活性的大分子介电增强剂;最后将大分子介电增强剂、过氧化物的引发剂b和聚丙烯树脂一起加入到螺杆捏合机中进行反应挤出,通过自由基接枝反应制备出高介电常数聚丙烯组合物。该方法制备出的聚丙烯组合物具有高的介电常数和低的介电损耗,非常适合用于薄膜电容器、锂电池隔膜等需要高介电常数和较低介电损耗的相关产品。
Need to check novelty before this filing date? Find Prior Art