A method for removing silicon from a nickel sulfate leach solution
CN117660777BActive Publication Date: 2026-08-28QUZHOU HUAYOU COBALT NEW MATERIAL CO LTD +1
Patent Information
- Application Number
- CN202211053657.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2022-08-31
- Publication Date
- 2026-08-28
- Estimated Expiration
- 2042-08-31
AI Technical Summary
Technical Problem
[0003]目前,针对高浓度硫酸镍浸出液中硅的去除方法普遍存在的问题是:在去除硅的同时引入铁、铝和氯元素,增加了渣量和有价金属夹带损失,并增加了设备使用负担
Benefits of technology
[0029]本发明具有以下有益效果:发明人创造性地利用金属粉、活性炭和阴离子型表面活性剂进行除硅反应,利用金属粉和活性炭形成小原电池,利用硫酸镍浸出液体系本身的电化学性质,使其周围产生电场及电势差,采用阴离子型表面活性剂为絮凝剂,在电场作用下使胶体硅沉积,固液分离得到硫酸镍净化后液。金属粉、活性炭本身不参与化学反应,因此不引入杂质元素,且可循环使用,降低了生产成本。
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Abstract
The application discloses a method for removing silicon from a nickel sulfate leaching solution and relates to the technical field of hydrometallurgy. The method for removing silicon from the nickel sulfate leaching solution comprises the following steps: mixing and reacting the nickel sulfate leaching solution with a silicon removal agent, wherein the silicon removal agent comprises metal powder, activated carbon and an anionic surfactant; and the metal powder is selected from at least one of copper powder and manganese powder. The silicon removal reaction is performed by using the metal powder, the activated carbon and the anionic surfactant, a small primary cell is formed by using the metal powder and the activated carbon, an electric field and a potential difference are generated around the nickel sulfate leaching solution system by using the electrochemical properties of the nickel sulfate leaching solution system, the anionic surfactant is used as a flocculant, and colloidal silicon is deposited under the action of the electric field, so that the purified nickel sulfate solution is obtained through solid-liquid separation. The metal powder and the activated carbon do not participate in the chemical reaction, so that no impurity elements are introduced, and the metal powder and the activated carbon can be recycled, thereby reducing the production cost.
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Citation Information
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