一种高活性仿生酶催化剂及其制备方法

By anchoring nano-metal particles in carbon nanotubes to prepare carbon-free biomimetic nanozyme catalysts, the problems of high overpotential and low capacity in lithium-oxygen batteries have been solved, achieving low reaction overpotential, large specific capacity and good cycle stability, thus promoting the advancement of novel energy storage technologies.

CN117673373BActive Publication Date: 2026-07-17BEIJING INST OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING INST OF TECH
Filing Date
2022-08-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The high overpotential and low actual capacity of existing lithium-oxygen batteries limit their application in long-range, high-safety pure electric vehicles. Traditional carbon catalysts cause large charging overpotentials and poor cycle performance, while noble metal catalysts have low capacity and are difficult to achieve both high capacity and low overpotential at the same time.

Method used

A carbon-free biomimetic nanozyme structure transition metal catalyst was prepared by anchoring nano-metal particles in carbon nanotubes through high-temperature carbon reduction, resulting in a catalyst with porous properties that mimics the structure of natural nanozymes, thereby enhancing catalytic activity and cycle stability.

Benefits of technology

This achievement enables metal-air batteries to exhibit low reaction overpotential, high specific capacity, and excellent rate performance, thereby improving battery cycle stability and promoting the development of new energy storage technologies.

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Abstract

本发明公开了一种高活性仿生酶催化剂及其制备方法。利用简单方便且产量丰富的合成方法制备出无碳仿生纳米酶正极催化剂,通过高温下碳的原位还原制备出高度分散均匀的纳米金属颗粒,结构仿生天然纳米酶,通过独特的结构设计暴露出更多催化活性位点,有利于气体的扩散与运输,为还原产物的生长提供了很好的框架,所组装的金属空气电池表现出优异的倍率性能和循环稳定性,并且反应过电位低,氧气还原和析出反应动力学得到大幅提升,本发明对新型储能技术的发展起着重要的推进作用。
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