基于量子点同质梯度结的光电探测器及其制备方法

By fabricating a photodetector based on a PIN homogeneous gradient junction and utilizing liquid-phase and solid-state ligand exchange methods, the problems of lattice mismatch and high-temperature performance degradation in traditional mid-wave infrared photodetectors were solved, achieving high carrier mobility and good performance at room temperature.

CN117693265BActive Publication Date: 2026-07-17BEIJING INST OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING INST OF TECH
Filing Date
2022-09-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional mid-wave infrared photodetectors are complex and costly to fabricate. Lattice mismatch and interface transport problems in heterojunctions lead to low photocurrent and rapid performance degradation at high temperatures. Traditional synthesis methods result in low mobility and responsivity.

Method used

By employing a mixed-phase ligand exchange method involving liquid-phase ligand exchange and solid-phase ligand exchange, strong N-type, weak N-type, intrinsic N-type, weak P-type, and strong P-type mercury telluride colloidal quantum dots are prepared and stacked in the vertical direction to form a PIN homogeneous gradient junction. This avoids lattice mismatch and interface transport problems, thereby improving carrier mobility and stabilizing the Fermi level.

Benefits of technology

It improves photocurrent collection capability, maintains good high-temperature performance, and realizes high-performance mid-wave photovoltaic infrared detection at room temperature.

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Abstract

本公开实施例涉及一种基于量子点同质梯度结的光电探测器及其制备方法,该制备方法包括:提供基底;基底的一侧形成有第一电极;基于液相配体交换制备N型量子点、弱N型量子点、本征型量子点、弱P型量子点以及P型量子点;在第一电极上依次成膜第一类型量子点层、弱第一类型量子点层、本征型量子点层、弱第二类型量子点层以及第二类型量子点层,并进行固态配体交换;其中,第一类型和第二类型分别为P型和N型中的一种;在第二类型量子点层背离第一电极的一侧形成第二电极。本公开实施例,通过将各类型的胶体量子点依次垂直堆叠,形成基于PIN同质梯度结的光电探测器,提供了可以在室温运行,且具有较好的探测性能的光电探测器。
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