改性多孔磁性金属有机框架复合生物炭的制备及应用方法

By modifying and pyrolyzing Ulva prolifera biomass at high temperature, a porous magnetic metal-organic framework composite biochar was prepared, which solved the problem of removing hexavalent chromium ions from dyeing and printing wastewater, achieved efficient adsorption and recovery, avoided secondary pollution, and has good application prospects.

CN117718017BActive Publication Date: 2026-07-17CHANGZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHANGZHOU UNIV
Filing Date
2023-09-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for efficiently removing hexavalent chromium ions from dyeing and printing industrial wastewater, and traditional methods may lead to secondary pollution and separation difficulties.

Method used

Potassium hydroxide and thiourea were used to modify the biomass of *Ulva prolifera*. Thiourea-modified porous biochar was prepared by high-temperature pyrolysis, and iron oxide and copper-based metal-organic frameworks were grown on its surface to construct a magnetic adsorbent. The adsorbent was recovered using magnetic separation technology.

Benefits of technology

It achieves efficient adsorption and recovery of hexavalent chromium ions, solves the problem of powder aggregation and difficulty in separation, reduces secondary pollution, and is simple to operate and energy-saving.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明属于生物质综合利用和废水处理技术领域,具体涉及一种改性多孔磁性金属有机框架复合生物炭的制备及应用方法。利用氢氧化钾和硫脲对浒苔生物质原料进行改性,再利用高温热解技术制备硫脲改性多孔生物炭,再在硫脲改性多孔生物炭表面生长四氧化三铁和铜基金属有机框架,解决四氧化三铁和铜基金属有机框架纳米颗粒的团聚与回收问题,构建磁性吸附剂,赋予浒苔生物炭新功能。研究改性多孔磁性金属有机框架复合生物炭在不同吸附条件下对水体中重金属铬离子的吸附,利用磁分离技术有效实现改性多孔磁性金属有机框架复合生物炭的高效富集回收,减少了二次污染的产生,推进重金属减排技术发展,具有良好的应用前景。
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