一种可重复使用的γ射线薄膜荧光探针及其制备方法与应用

A thin-film fluorescent probe made by mixing rhodamine B hydrazide and polyvinylidene chloride utilizes hydrogen chloride generated by gamma ray irradiation to open the ring and restore the closed ring, solving the problems of portability, reusability and cost of existing gamma ray detection methods, and realizing efficient and simple gamma ray detection.

CN117720904BActive Publication Date: 2026-07-17INST OF CHEM CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INST OF CHEM CHINESE ACAD OF SCI
Filing Date
2022-09-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing gamma-ray detection methods rely on large instruments, the detection materials are difficult to prepare and time-consuming, liquid fluorescent probes are not portable, have high detection costs and cannot be reused, and are sensitive to environmental humidity.

Method used

A solid-state thin-film fluorescent probe made of a mixture of rhodamine B hydrazide and polyvinylidene chloride was used. The hydrogen chloride generated by gamma irradiation caused the rhodamine B hydrazide to open its ring and emit light. After detection, the ring was restored to closed state with triethylamine so that it could be reused.

Benefits of technology

It enables portable, rapid, and low-cost gamma-ray detection. The detection process is unaffected by ambient humidity, and the probe is reusable, reducing detection costs and improving efficiency.

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Abstract

本发明公开一种可重复使用的γ射线薄膜荧光探针及其制备方法与应用。本发明提供了罗丹明B酰肼与聚偏二氯乙烯在作为检测γ射线的荧光探针材料中的应用;本发明还提供一种γ射线薄膜荧光探针,为由罗丹明B酰肼与聚偏二氯乙烯于基底上形成的薄膜;本发明还提供了γ射线薄膜荧光探针的制备方法、使用方法及重置方法。本发明所提供的薄膜作为荧光探针,具有灵敏度高、精密度好、便携性好、检测方法简单快速且可重复使用的优点;利用该荧光探针,可实现对γ射线的快速检测。同时该荧光探针的制作成本较低、制备方法简单,更有利于推广使用。
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