一种钠化提钒渣氢基直接还原制备金属化球团的方法

By combining high-pressure roller milling, acid leaching, and oxidative roasting with hydrogen-based vertical furnace reduction, the problem of pelletizing caused by alkali metal and aluminosilicate impurities in sodium vanadium extraction slag was solved. This method achieved efficient separation and high recovery of iron and titanium, reduced energy consumption and carbon emissions, and provided high-quality furnace feed for blast furnaces or electric furnaces.

CN117737331BActive Publication Date: 2026-07-17CENT SOUTH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2024-01-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, the high content of alkali metals and aluminosilicate impurities in sodium vanadium extraction slag leads to severe pellet reduction and pulverization, poor titanium-iron separation effect, low resource recovery rate, and high energy consumption and CO2 emissions in blast furnace method or pre-reduction-melting method, making it difficult to achieve effective utilization.

Method used

By combining high-pressure roller milling, acid leaching, and oxidative roasting with hydrogen-based vertical furnace reduction, alkali metals and aluminosilicate impurities in vanadium extraction slag are removed. Hydrogen-based reducing agents and electromagnetic induction heating technology are used to achieve effective separation and efficient reduction of iron and titanium.

Benefits of technology

It significantly improves the grade and recovery rate of iron and titanium in vanadium extraction slag, reduces production costs and carbon emissions, provides high-quality metallized pellets for blast furnace or electric furnace smelting, and simplifies the process.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明属于冶金工程技术领域,具体公开了一种钠化提钒渣氢基直接还原制备金属化球团的方法,包括:将钒钛磁铁精矿钠化提钒渣进行造球并完成焙烧,经高压辊磨后进行酸浸,获得酸浸渣;将酸浸渣经浓缩、脱水后进行造球,获得生球;将生球经氧化焙烧固化、气基竖炉还原,获得金属化率为85~92%的金属化球团;其中,所述氢基竖炉包括上部的还原区和下部的电磁感应热处理区。本发明成功解决了钒钛磁铁矿钠化提钒渣球团还原膨胀率高、还原粉化率大的难题,提高了提钒渣中钛、铁品位,消除了提钒渣堆存带来的环境污染问题,将提钒渣制备为高品位钛、铁的金属化球团,为钒钛磁铁矿直接钠化提钒工艺的推广创造了良好条件。
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