一种从低Li高Na溶液中回收Li的萃取剂及方法

By using a synergistic system of neutral extractant TBP and chelating extractant Lix54-100, along with the modifier 2-octanol, the problem of efficient lithium extraction from low-grade lithium mica solutions was solved, achieving high extraction rate and high separation effect. This method is suitable for lithium recovery from various low-Li, high-Na solutions.

CN117737426BActive Publication Date: 2026-07-17BEIJING UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING UNIV OF TECH
Filing Date
2023-12-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for efficiently extracting lithium from low-grade lepidolite solutions, and traditional extraction methods are costly and cumbersome in low-Li, high-Na solutions, failing to meet the demand for efficient lithium resource recovery.

Method used

A synergistic extraction system was formed by neutral extractant TBP and chelating extractant Lix54-100. Octyl alcohol was used as a modifier and sulfonated kerosene as a diluent. The composition of the extractant and the extraction conditions were optimized to improve the lithium extraction rate and the lithium/sodium separation effect.

Benefits of technology

It achieves efficient lithium extraction, improves lithium extraction rate and lithium/sodium separation coefficient, is simple to operate, and is suitable for low-Li, high-Na solutions from different material sources, meeting the needs of low-grade lithium resource recovery.

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Abstract

本发明涉及含锂资源湿法冶金分离和回收利用领域,具体涉及一种从低Li高Na溶液中提取Li的萃取剂及方法。本发明提供的萃取剂包括中性萃取剂、螯合萃取剂、改性剂和稀释剂;所述中性萃取剂包括TBP,所述螯合萃取剂包括Lix54‑100。本发明通过添加中性萃取剂TBP,与螯合萃取剂Lix54‑100形成协同萃取体系,并优选以仲辛醇为改性剂,磺化煤油为稀释剂,对低Li高Na锂云母除杂液中的Li协同萃取,提高了单一螯合萃取剂Lix54‑100对Li的萃取率以及Li / Na分离系数,具有Li一次萃取率高,操作简单,生产效率高等特点。
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