多孔钨基材料及其制备方法

By combining SiO2/C composite materials with tungsten powder of different particle sizes, the problem of low density in porous tungsten-based materials was solved, and porous tungsten-based materials with high density and excellent microstructure uniformity were prepared, thereby improving the hardness, heat resistance and corrosion resistance of the materials.

CN117758120BActive Publication Date: 2026-07-17XIAN BAODE JIUTU NEW MATERIAL CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XIAN BAODE JIUTU NEW MATERIAL CO LTD
Filing Date
2023-11-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the prior art, porous tungsten-based materials have a relatively low density, which affects the material's density and high-temperature resistance.

Method used

Porous tungsten-based materials were prepared by using SiO2/C composite material as a preform and through cold isostatic pressing and sintering processes. The dispersibility of SiO2/C material and the wettability of carbon layer were utilized to promote copper infiltration. Combined with tungsten powder of different particle sizes to fill the pores, the density and microstructure uniformity of the material were improved.

Benefits of technology

It improves the hardness, heat resistance and corrosion resistance of porous tungsten-based materials, enhances the fluidity and permeability of the copper phase, and improves the overall strength and density of the material.

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Abstract

本发明公开了多孔钨基材料的制备方法,包括:先将SiO2球分散于乙醇和酒精,再依次向其中加入十六烷基三甲基溴化铵和氨水的混合液、间苯二酚和甲醛的混合液,经过洗涤、干燥后得到酚醛树脂包覆的二氧化硅球,将所述酚醛树脂包覆的二氧化硅球置于管室炉中碳化,得到SiO2 / C材料;将所述SiO2 / C材料与两种粒径的钨粉混合,得到W‑SiO2 / C复合粉末;将所述W‑SiO2 / C复合粉末装入模具进行冷等静压,得到钨骨架生坯;对所述钨骨架生坯进行烧结,得到钨骨架烧结坯;将所述钨骨架烧结坯与铜块置于氢气炉中进行渗铜,得到钨‑铜复合材料。本发明还公开了多孔钨基材料,由上述制备方法得到,其密度和整体组织的均匀性较高。
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