一种超亲水木材基乳液分离膜材料及其制备方法和应用

By constructing a dense regenerated cellulose layer on a wood substrate, the problems of oil-water separation membrane materials being easily contaminated by oil and having excessively large pore structures in existing technologies are solved, achieving efficient and biodegradable emulsified oil separation.

CN117771978BActive Publication Date: 2026-07-17NANJING GREEN MFG IND INNOVATION RES INST +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANJING GREEN MFG IND INNOVATION RES INST
Filing Date
2023-12-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing superhydrophobic/oleophilic oil-water separation membrane materials are easily contaminated by oil in practical applications, and are not suitable for gravity-driven separation, making it difficult to effectively remove emulsified oil. Furthermore, the pore structure of natural wood is too large, making it difficult to effectively retain small-sized emulsified oil.

Method used

Using porous wood substrate material, a dense regenerated cellulose layer is constructed on the wood surface through the dissolution and regeneration of plant cellulose, forming a superhydrophilic/underwater superoleophobic surface wetting property. Combined with hydrogen bonding, a tightly bound membrane structure is formed, and the pore structure is controlled to achieve high throughput and high separation efficiency.

Benefits of technology

It achieves effective retention and separation of small-sized emulsified oil droplets, the membrane structure is not easily contaminated by oil, the preparation process is green and environmentally friendly, meets the needs of sustainable development, and is low in cost and biodegradable.

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Abstract

本发明涉及一种超亲水木材基乳液分离膜材料及其制备方法和应用,所述超亲水木材基乳液分离膜材料包括:多孔木材基底膜材料以及修饰于多孔基底膜材料表面的再生植物纤维气凝胶层。本发明创造性地提出以木材为多孔基底材料,通过植物纤维素溶解再生,在木材表面构建致密的再生纤维素层。丰富的羟基官能团使得再生纤维素层具有超亲水 / 水下超疏油的表面润湿特性,使得其表现出强力抵抗油黏附性,不易被油污染。同时致密的膜层结构可实现小尺寸乳化油滴的有效截留分离,且截留分子量可控。且膜层结构与基底材料是通过氢键作用紧密结合的,有效避免了物理涂覆修饰层的脱落问题。
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