一种钙钛矿基双功能催化剂及其制备方法和应用

By depositing vertical graphene arrays on the surface of perovskite oxides, the problem of low electronic conductivity of perovskite oxides was solved, achieving efficient charge transfer and structural stability in zinc-air batteries, improving the electrocatalytic performance of catalysts and the commercial application of flexible zinc-air batteries.

CN117790815BActive Publication Date: 2026-07-17CHINA UNIV OF GEOSCIENCES (WUHAN)

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA UNIV OF GEOSCIENCES (WUHAN)
Filing Date
2023-12-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing perovskite oxides have low electronic conductivity, which limits their application in zinc-air batteries. Furthermore, catalysts combined with graphene have poor stability, and their electrocatalytic performance needs to be improved.

Method used

A vertical graphene array was deposited on the surface of a perovskite oxide using plasma-enhanced chemical vapor deposition (PECVD) to form a core-shell structured perovskite-based bifunctional catalyst. The rapid growth of the vertical graphene array was promoted by dissolving the metal portion of the perovskite surface under a medium-temperature reducing atmosphere.

Benefits of technology

It significantly improves the electronic conductivity and catalytic activity of perovskite oxides, enhances the charge transfer rate and structural stability of zinc-air batteries, exhibits good rate performance and cycle performance, and expands the commercial application of flexible zinc-air batteries.

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Abstract

本发明公开了一种钙钛矿基双功能催化剂及其制备方法和应用。本发明的一种钙钛矿基双功能催化剂的制备方法,利用等离子体增强化学气相沉积技术在钙钛矿型氧化物表面沉积垂直石墨烯阵列制得钙钛矿基双功能催化剂;其中,所述钙钛矿型氧化物的化学式为PrBaxSr1‑xCo2‑yMyO5+δ,其中x=0~1.0,M为B位掺杂过渡金属或贵金属,金属掺杂比例y值不大于0.5。本发明的核壳结构的钙钛矿基双功能催化剂,可在碱性条件下保持优异的氧还原和氧析出反应双功能催化活性,应用于锌空气电池阴极催化剂表现出良好的倍率和循环稳定性。
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