一种复分解制备六氟磷酸锂的方法

The preparation of lithium hexafluorophosphate by reacting the organic phase extracted with hydrofluoric acid using phosphoric acid via metathesis method solves the problems of low yield and high equipment requirements in the existing technology, and realizes the preparation of lithium hexafluorophosphate with high efficiency and low cost.

CN117819575BActive Publication Date: 2026-07-17GUIZHOU PHOSPHATING NEW ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUIZHOU PHOSPHATING NEW ENERGY TECH CO LTD
Filing Date
2023-12-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for preparing lithium hexafluorophosphate suffer from low yields and high requirements for reaction equipment, resulting in high costs for industrial production.

Method used

Lithium hexafluorophosphate is prepared by metathesis, using phosphoric acid to extract the organic phase as raw material. Potassium hexafluorophosphate is generated by the reaction of phosphoric acid and hydrofluoric acid, and then reacted with lithium chloride and catalyst to generate lithium hexafluorophosphate. This method avoids gas mixing and reduces equipment requirements.

Benefits of technology

It improves the yield of lithium hexafluorophosphate, reduces the corrosiveness requirements of equipment and production costs, reduces environmental pollution, and simplifies equipment design.

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Abstract

本发明属于化学合成技术领域,具体涉及一种复分解制备六氟磷酸锂的方法,包括S1:往磷酸萃取有机相中加入氢氟酸,搅拌反应得到料液A,往料液A加入氢氧化钾溶液并搅拌分散,停止搅拌后反应产物六氟磷酸钾进入水相,将两相分离后的水相进行过滤,滤饼为六氟磷酸钾粗品;S2:将六氟磷酸钾粗品与高纯水混合,进行溶解,然后对溶液降温结晶、真空干燥后得到高纯度的六氟磷酸钾;S3:向金属反应容器置中加入碳酸二甲酯与碳酸二乙酯的混合溶液,然后加入氯化锂与高纯六氟磷酸钾,再加入催化剂,过滤,滤饼经干燥后得到六氟磷酸锂液体产品。解决了现有技术存在的六氟磷酸锂制备方法存在的对反应设备要求高,导致工业化生产成本高的技术问题。
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