一种共价有机骨架 / Mxene复合材料及其制备方法和应用

By electrostatically combining imidazole-based covalent organic framework materials with MXene nanosheets to form covalent organic framework/Mxene composite materials, the conductivity and stability issues of non-metallic electrocatalysts in the electrocatalytic hydrogen evolution reaction were solved, achieving highly efficient electrocatalytic hydrogen evolution performance.

CN117822043BActive Publication Date: 2026-07-17JILIN UNIVERSITY
View PDF 2 Cites 0 Cited by

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JILIN UNIVERSITY
Filing Date
2023-12-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing non-metallic electrocatalysts suffer from poor conductivity and insufficient electrochemical stability in the electrocatalytic hydrogen evolution reaction, leading to a decrease in catalytic activity.

Method used

An imidazole-based covalent organic framework material is combined with MXene nanosheets through electrostatic interaction to form a covalent organic framework/MXene composite material. The catalytic active sites of the imidazole-based covalent organic framework material and the excellent conductivity of MXene are utilized to promote electron transitions and improve electrocatalytic performance.

Benefits of technology

It achieves highly efficient electrocatalytic hydrogen evolution performance, with low overpotential and good electrochemical stability, surpassing most non-pyrolytic MXene-based catalysts.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN117822043B_ABST
    Figure CN117822043B_ABST
Patent Text Reader

Abstract

本发明提供了一种共价有机骨架 / Mxene复合材料及其制备方法和应用,属于共价有机骨架材料技术领域。咪唑基共价有机骨架材料具有催化HER活性位点,MXene具有优异的导电性和大活性表面积,本发明将咪唑基共价有机骨架材料与MXene复合之后表现出较高的HER催化活性。本发明将具有咪唑基阳离子的COF与携带有负电荷的MXene复合,二者通过静电力结合,使其电子云轨道部分重叠,在催化过程中促进电子跃迁。实施例结果表明,在咪唑基共价有机骨架材料与MXene以3:1的质量比复合后,在10mA cm‑2的电流密度下表现出相当低的HER过电位,仅为186mV。
Need to check novelty before this filing date? Find Prior Art

Citation Information

Patent Citations

  • Composite photocatalytic material attached with MXene phase promoter as well as preparation method and application of composite photocatalytic material

    CN115463677A

  • Covalent organic framework / MXene composite film material as well as preparation method and application thereof

    CN116759520A