一种MTO废催化剂为原料的砌块及其制备方法

By combining the magnesium oxychloride cementing system with spent MTO catalyst, building blocks were prepared, which solved the problem of difficult bonding between spent MTO catalyst and silicate cement. This achieved the resource utilization of spent catalyst and improved block performance, while reducing environmental pollution and energy consumption.

CN117843338BActive Publication Date: 2026-07-17PUCHENG CLEAN ENERGY CHEM CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PUCHENG CLEAN ENERGY CHEM CO LTD
Filing Date
2023-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Due to carbon residue, large specific surface area, and small pore volume, MTO spent catalysts are difficult to bond with silicate cement, resulting in poor overall performance of the prepared blocks. Furthermore, traditional treatment methods pose environmental pollution and energy consumption problems.

Method used

A building block was prepared by combining a magnesium oxychloride gelling system with MTO waste catalyst, and by adding lightly calcined magnesium powder, magnesium chloride hexahydrate and modifiers to form a stable gelling system. The particle size distribution was improved by using fillers, and the block was cured at room temperature.

Benefits of technology

This method enables the resource utilization of spent MTO catalysts, reduces environmental pollution, improves the overall performance of building blocks, reduces energy consumption, meets building material standards, and the preparation process is environmentally friendly and efficient.

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Abstract

本发明公开了一种MTO废催化剂为原料的砌块及其制备方法,属于废催化剂回收以及建筑材料技术领域。该MTO废催化剂为原料的砌块MTO废催化剂50‑70份;轻烧镁粉14.6‑26.6份;填料5‑10份;六水氯化镁8.4‑16.6份;改性剂0.1‑1.5份。其中,所述MTO废催化剂的烧失量<15%;所述填料的含水率≤8%。同时还提供了本发明的MTO废催化剂为原料的砌块的制备方法。本发明可以解决由于MTO废催化剂因比表面积大,孔容小难与硅酸盐水泥结合,导致制备的砌块综合性能低的问题,可以真正实现MTO废催化剂的资源化利用有效稳定的解决MTO废催化剂大量堆放的问题,降低对环境的污染,同时制备的砌块综合性能高。
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