一种氮杂醌基聚合物材料及其制备方法和应用

By designing azaquinone-based polymer material, the problems of low efficiency and high cost of existing photocatalytic materials have been solved, and efficient preparation of H2O2 at room temperature and pressure has been achieved, improving the conversion efficiency of solar energy to chemical energy.

CN117843931BActive Publication Date: 2026-07-17JINGGANGSHAN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JINGGANGSHAN UNIVERSITY
Filing Date
2024-01-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing photocatalytic materials are inefficient in preparing H2O2, and traditional methods are costly and pollute the environment. Existing inorganic materials have a narrow light absorption range and low solar energy utilization, while organic polymers lack specific redox centers.

Method used

Design a azirquinone-based polymer material to construct a polymer with precise band structure and active center through the coupling reaction of azirquinone and electron-rich compounds. Utilize the two-electron redox properties of azirquinone to promote the reduction of O2 and the oxidation of H2O to H2O2.

Benefits of technology

It achieves efficient H2O2 production from H2O and O2 under ambient temperature and pressure and visible light excitation, improving the utilization efficiency of photogenerated electrons and holes, enhancing photocatalytic reaction efficiency, and reducing production costs.

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Abstract

本发明属于聚合物材料技术领域,具体涉及一种用于光催化制备H2O2的氮杂醌基聚合物材料及其制备方法和应用。本发明的氮杂醌基聚合物材料,以富电子的1,3,5‑三(4‑乙炔基苯基)苯、三苯胺、1,1,2,2‑四(对乙炔基苯基)乙烯、苯并噻吩、四硫富瓦烯和咔唑类化合物为电子给体,以缺电子的氮杂醌为电子受体及氧化还原中心,是一种具有精确能带结构(导带、价带及带隙宽度)和活性中心空间分离的氮杂醌基聚合物材料。光催化制备H2O2时,利用电子受体氮杂醌作为O2还原位点,电子给体作为H2O氧化位点,促使H2O氧化失去的电子精准传递到O2还原中,从而实现常温常压下高效制备H2O2,提高太阳能到化学能总体转化效率。
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