一种合成磷酸三丁酯用催化剂、制备方法及其应用

By using a catalyst generated from N-methylimidazole, dibromobutane, and heteropolyacids, the problems of low purity and yield of tributyl phosphate in existing technologies have been solved, achieving high catalytic efficiency and stability, making it suitable for large-scale production.

CN117884178BActive Publication Date: 2026-07-17HANGZHOU QIANYANG TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HANGZHOU QIANYANG TECH
Filing Date
2024-01-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing methods for synthesizing tributyl phosphate, the purity of the catalyst is no higher than 99.93%, and the yield is no higher than 78.4%. Furthermore, the synthesis steps of pyridine-based and supported molecular sieve catalysts are complex and not suitable for large-scale production.

Method used

Using N-methylimidazole, dibromobutane, and heteropolyacids as catalyst feedstocks, functional bromide salts are generated and react with heteropolyacids to form catalysts with high catalytic activity and chemical stability. The catalytic effect is improved by controlling the feedstock ratio and reaction conditions.

Benefits of technology

The yield of tributyl phosphate was significantly improved to 92.45-92.72%, the purity reached 99.993-99.995%, and good chemical stability was maintained.

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Abstract

本申请涉及化学产品的合成领域,具体公开了一种合成磷酸三丁酯用催化剂、制备方法及其应用,所用原料包括以下重量份的组份:N‑甲基咪唑31‑34份;二溴丁烷42‑45份;有机溶剂30‑32份;杂多酸350‑400份;所述二溴丁烷为1,4‑二溴丁烷或1,2‑二溴丁烷;其制备方法为:将N‑甲基咪唑和二溴丁烷溶于有机溶剂中并混合均匀,然后向体系内通入惰性气体,并在65‑73℃的温度下搅拌回流,之后经过减压抽滤,洗涤干燥,得到初产物,并与杂多酸混合溶于水中,持续搅拌并反应,经过减压抽滤,洗涤,干燥,得到合成磷酸三丁酯用催化剂。本申请制得的合成磷酸三丁酯用催化剂具有高催化性,可用于催化合成高纯度的磷酸三丁酯。
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