柴油加氢精制催化剂及其制备和应用

By introducing pre-made Brønsted acid-containing alumina material into the diesel hydrotreating catalyst support, the acid content and acid strength were controlled, solving the problems of catalyst deactivation due to coking and uncontrollable acid strength, improving desulfurization efficiency and activity, and reducing reaction temperature.

CN117899887BActive Publication Date: 2026-07-17PETROCHINA CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PETROCHINA CO LTD
Filing Date
2022-10-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing diesel hydrotreating catalysts suffer from problems such as high deactivation rates due to coking, uncontrollable acid strength, and easy formation of coke at Lewis acid sites. These issues lead to decreased catalyst activity and poor reactant proximity, thus affecting desulfurization efficiency.

Method used

By introducing pre-made alumina material containing Brønsted acid into the catalyst support, the amount and strength of acid can be controlled to promote the direct desulfurization and hydroisomerization-direct desulfurization reaction pathways, reduce hydrogen consumption, and improve desulfurization activity.

Benefits of technology

The catalyst achieved a low carbon deposit deactivation rate, which improved the efficiency and activity of diesel hydrodesulfurization, reduced the reaction temperature, and promoted the simultaneous removal of sulfur and nitrogen oxides.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种含B酸的加氢催化剂,所述含B酸的加氢催化剂包括载体和活性金属,所述载体为含B酸的氧化铝载体,所述活性金属为Co、Mo、Ni、W中的一种或几种;以所述催化剂的总重量为100%计,其包含70‑85%的含B酸的氧化铝载体和15‑30%的活性金属氧化物。本发明还公开其制备方法和应用。本发明通过将预制的含B酸的氧化铝材料引入催化剂载体,实现了催化剂载体B酸中心的可控引入。本发明所制备的催化剂加氢脱硫活性得到大幅度提高。
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