一种全无铅铕基钙钛矿纳米晶及其制备方法与应用

CsEuX3 nanocrystals were synthesized by thermal injection, introducing Tb3+ and Eu3+ ions. This solved the problem of unsatisfactory monochromatic emission of lead-free perovskite nanocrystals, achieving efficient blue, green, and red light emission, expanding the display color gamut, improving display effect, and applying it to multiple optoelectronic fields.

CN117902611BActive Publication Date: 2026-07-17FUDAN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
FUDAN UNIVERSITY
Filing Date
2023-12-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lead-free perovskite nanocrystal materials have unsatisfactory monochromatic emission, which prevents them from expanding the display color gamut and improving the display effect.

Method used

Using a hot-injection method, cesium salts, europium salts, and organic halogens as raw materials, organic acids and organic amines as ligands, and high-boiling-point olefins as solvents, lead-free europium-based perovskite nanocrystals with a structure of CsEuX3 were synthesized. Tb3+ and Eu3+ ions were introduced to achieve energy transfer from the perovskite nanocrystals to rare earth ions, thus preparing nanocrystals that emit blue, green, and red light.

Benefits of technology

The prepared CsEuX3 nanocrystals have high photoluminescence quantum efficiency and high monochromaticity, and can be widely used in solar cells, light-emitting diodes, lasers, backlight displays and communications.

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Abstract

本发明涉及一种全无铅铕基钙钛矿纳米晶及其制备方法与应用,制备方法包括如下步骤:S1、在三价铕盐中加入有机胺发生还原反应,得到Eu2+‑有机胺复合物,作为二价铕前驱体;S2、将S1步骤得到的Eu2+‑有机胺复合物、铯盐、有机酸、高沸点烯烃溶剂混合后得到混合液,将混合液发生真空脱气,结束后加入有机卤素盐进行高温反应,最后进行冰浴;S3、将S2步骤得到的混合液与非极性溶剂混合,离心后得到结构组成为CsEuX3的无铅铕基钛矿纳米晶,其中X表示为卤素。与现有技术相比,本发明采用热注入的方法,有效合成高光致发光量子效率、高单色性CsEuX3结构基质的纳米晶,分别实现蓝、红、绿光发射。
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