一种新型硅负极粘结剂及其制备方法及应用

By using a novel binder CG@PEO composed of CS, GO and PEO, the problems of volume expansion and low conductivity of silicon-carbon anode materials in lithium-ion batteries are solved, thereby improving the cycle life and electrochemical performance of the battery.

CN117903740BActive Publication Date: 2026-07-17SUN YAT SEN UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SUN YAT SEN UNIV
Filing Date
2023-12-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing silicon-carbon anode materials suffer from problems such as volume expansion, low conductivity, and insufficient interfacial compatibility in lithium-ion batteries, leading to battery cycle life and performance degradation.

Method used

A novel binder composed of chondroitin sulfate (CS), graphene oxide (GO), and polyethylene oxide (PEO) is used to form CG@PEO binder through a polymerization reaction, which improves the ion conductivity, electronic conductivity, and interfacial compatibility of silicon anodes, and enhances the cohesion of the electrode sheets and the dispersibility of the slurry.

Benefits of technology

It improves the cycle stability and rate performance of silicon-carbon anodes, and enhances the long-term stability and electrochemical energy storage performance of lithium-ion batteries.

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Abstract

本发明公开了一种新型硅负极粘结剂及其制备方法及应用,由如下组分和重量份数组成:硫酸软骨素0.5~10、氧化石墨烯0.5~5和聚氧化乙烯1~100。本发明通过简便的工艺步骤和低成本的原材料制得了一种具有高导离子和高导电子的新型硅负极粘结剂CG@PEO,通过聚氧化乙烯(PEO)氧化石墨烯(GO)和硫酸软骨素(CS)的交联网络实现硅负极的高导离子、高导电子以及界面相容性,能够有效缓解硅碳负极在长时间循环使用中发生容量衰减的问题,为锂离子电池长期稳定循环提供保障。
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